TY - JOUR
T1 - (4,7-Dimethyl-1,10-phenanthroline)(ethylenediamine)platinum(II) dichloride tris(deuterium oxide) solvate
AU - Brodie, Craig R.
AU - Turner, Peter
AU - Wheate, Nial J.
AU - Aldrich-Wright, Janice R.
PY - 2006/11
Y1 - 2006/11
N2 - In the molecule of the title compound, [Pt(C14H 12N2)-(C2H4D4N 2)]Cl2·3D2O, the complex dication has squareplanar coordination to the PtII atom from N-donor atoms. A small tilt of 4.34 (6)° is observed between the plane of the phenanthroline (phen) ligand and the coordination plane. The phen ligands are assembled along [010], with π-π stacking interactions between phen ligands of interleaved complexes. The structure also reveals hydrogen-bond interactions between the complex ion, its counter-ions and the solvent molecules. The introduction of methyl residues onto the phen ligand at positions 4 and 7 does not appear to alter the geometry of the complex significantly.
AB - In the molecule of the title compound, [Pt(C14H 12N2)-(C2H4D4N 2)]Cl2·3D2O, the complex dication has squareplanar coordination to the PtII atom from N-donor atoms. A small tilt of 4.34 (6)° is observed between the plane of the phenanthroline (phen) ligand and the coordination plane. The phen ligands are assembled along [010], with π-π stacking interactions between phen ligands of interleaved complexes. The structure also reveals hydrogen-bond interactions between the complex ion, its counter-ions and the solvent molecules. The introduction of methyl residues onto the phen ligand at positions 4 and 7 does not appear to alter the geometry of the complex significantly.
UR - http://www.scopus.com/inward/record.url?scp=33750858154&partnerID=8YFLogxK
U2 - 10.1107/S1600536806043376
DO - 10.1107/S1600536806043376
M3 - Article
AN - SCOPUS:33750858154
SN - 1600-5368
VL - 62
SP - m3137-m3139
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 11
ER -