TY - JOUR
T1 - (5,6-Dimethyl-1,10-phenanthroline)(2-{[2-(diphenylphosphanyl)benzylidene]amino}ethan-1-amine)platinum(II) dinitrate methanol disolvate
AU - Jurisinec, Ashley
AU - Zhang, Yingjie
AU - Aldrich-Wright, Janice R.
PY - 2025/4/1
Y1 - 2025/4/1
N2 - The title compound, [Pt(C14H12N2)(C21H21N2P)](NO3)2·2CH3OH, is a platinum(II) complex, which crystallizes in a monoclinic (P21/c) space group. The complex exhibits a distorted square-planar geometry, which includes a monodentate 5,6-dimethyl-1,10-phenanthroline ligand and a tridentate 2-{[2-(diphenylphosphanyl)benzylidene]amino}ethan-1-amine ligand. The structure reveals both intra- and intermolecular π-stacking interactions between the phenanthroline and phosphine rings. Hydrogen bonding is observed between the complex ion, nitrate counter-ions and solvent molecules.
AB - The title compound, [Pt(C14H12N2)(C21H21N2P)](NO3)2·2CH3OH, is a platinum(II) complex, which crystallizes in a monoclinic (P21/c) space group. The complex exhibits a distorted square-planar geometry, which includes a monodentate 5,6-dimethyl-1,10-phenanthroline ligand and a tridentate 2-{[2-(diphenylphosphanyl)benzylidene]amino}ethan-1-amine ligand. The structure reveals both intra- and intermolecular π-stacking interactions between the phenanthroline and phosphine rings. Hydrogen bonding is observed between the complex ion, nitrate counter-ions and solvent molecules.
KW - crystal structure
KW - platinum(II)
KW - triphenylphosphine
KW - π-stacking
UR - http://www.scopus.com/inward/record.url?scp=105002687892&partnerID=8YFLogxK
U2 - 10.1107/S2056989025001847
DO - 10.1107/S2056989025001847
M3 - Article
AN - SCOPUS:105002687892
SN - 2056-9890
VL - 81
SP - 275
EP - 278
JO - Acta Crystallographica Section E: Crystallographic Communications
JF - Acta Crystallographica Section E: Crystallographic Communications
ER -