A large dinuclear Fe(II) triple helicate demonstrating a two-step spin crossover

Kyle J. Howard-Smith, Alexander R. Craze, Hikaru Zenno, Junya Yagyu, Shinya Hayami, Feng Li

Research output: Contribution to journalArticlepeer-review

15 Citations (Scopus)

Abstract

Reported herein, the synthesis as well as the structural and magnetic characterisation of the largest reported dinuclear Fe(II) triple helicate system to exhibit spin crossover—and also a rare example of a 273° helical twist using aromatic spacers—is presented, with exploration of the two-step spin-transition observed.
Original languageEnglish
Pages (from-to)8838-8841
Number of pages4
JournalChemical Communications
Volume56
Issue number62
DOIs
Publication statusPublished - 2020

Keywords

  • ligands
  • magnetic properties

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