A large dinuclear Fe(II) triple helicate demonstrating a two-step spin crossover

Kyle J. Howard-Smith; Alexander R. Craze; Hikaru Zenno; Junya Yagyu; Shinya Hayami; Feng Li

doi:10.1039/D0CC03708G

A large dinuclear Fe(II) triple helicate demonstrating a two-step spin crossover

Kyle J. Howard-Smith
, Alexander R. Craze
, Hikaru Zenno
, Junya Yagyu
, Shinya Hayami
, Feng Li

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

Reported herein, the synthesis as well as the structural and magnetic characterisation of the largest reported dinuclear Fe(ii) triple helicate system to exhibit spin crossover - and also a rare example of a 273° helical twist using aromatic spacers - is presented, with exploration of the two-step spin-transition observed.

Original language	English
Pages (from-to)	8838-8841
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	62
DOIs	https://doi.org/10.1039/D0CC03708G
Publication status	Published - 11 Aug 2020

Bibliographical note

Publisher Copyright:
© The Royal Society of Chemistry.

Keywords

ligands
magnetic properties

Access to Document

10.1039/D0CC03708G

Cite this

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abstract = "Reported herein, the synthesis as well as the structural and magnetic characterisation of the largest reported dinuclear Fe(ii) triple helicate system to exhibit spin crossover - and also a rare example of a 273° helical twist using aromatic spacers - is presented, with exploration of the two-step spin-transition observed.",

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author = "Howard-Smith, \{Kyle J.\} and Craze, \{Alexander R.\} and Hikaru Zenno and Junya Yagyu and Shinya Hayami and Feng Li",

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year = "2020",

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doi = "10.1039/D0CC03708G",

language = "English",

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AU - Howard-Smith, Kyle J.

AU - Craze, Alexander R.

AU - Zenno, Hikaru

AU - Yagyu, Junya

AU - Hayami, Shinya

AU - Li, Feng

PY - 2020/8/11

Y1 - 2020/8/11

N2 - Reported herein, the synthesis as well as the structural and magnetic characterisation of the largest reported dinuclear Fe(ii) triple helicate system to exhibit spin crossover - and also a rare example of a 273° helical twist using aromatic spacers - is presented, with exploration of the two-step spin-transition observed.

AB - Reported herein, the synthesis as well as the structural and magnetic characterisation of the largest reported dinuclear Fe(ii) triple helicate system to exhibit spin crossover - and also a rare example of a 273° helical twist using aromatic spacers - is presented, with exploration of the two-step spin-transition observed.

KW - ligands

KW - magnetic properties

UR - http://hdl.handle.net/1959.7/uws:56561

U2 - 10.1039/D0CC03708G

DO - 10.1039/D0CC03708G

M3 - Article

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SN - 1359-7345

VL - 56

SP - 8838

EP - 8841

JO - Chemical Communications

JF - Chemical Communications

IS - 62

ER -

A large dinuclear Fe(II) triple helicate demonstrating a two-step spin crossover

Abstract

Bibliographical note

Keywords

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