A mixed-spin molecular square with a hybrid [2Ã— 2]grid/metallocyclic architecture

Feng Li; Jack K. Clegg; Laurence Goux-Capes; Guillaume Chastanet; Deanna M. D'Alessandro; Jean-François Létard; Cameron J. Kepert

doi:10.1002/anie.201007409

A mixed-spin molecular square with a hybrid [2Ã— 2]grid/metallocyclic architecture

Feng Li
, Jack K. Clegg
, Laurence Goux-Capes
, Guillaume Chastanet
, Deanna M. D'Alessandro
, Jean-François Létard
, Cameron J. Kepert

School of Science

Research output: Contribution to journal › Article › peer-review

41 Citations (Scopus)

Abstract

Hunting high and low: A cyanide-bridged rhombic mixed-spin Fe II-FeII complex that features low-spin (LS) and high-spin (HS) FeII centers was prepared by self-assembly including the decomposition of SeCN. The structural motif represents a hybrid [2Ã— 2]grid/metallocyclic architecture (see picture).

Original language	English
Pages (from-to)	2820-2823
Number of pages	4
Journal	Angewandte Chemie (International Edition)
Volume	50
Issue number	12
DOIs	https://doi.org/10.1002/anie.201007409
Publication status	Published - 2011

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abstract = "Hunting high and low: A cyanide-bridged rhombic mixed-spin Fe II-FeII complex that features low-spin (LS) and high-spin (HS) FeII centers was prepared by self-assembly including the decomposition of SeCN. The structural motif represents a hybrid [2{\~A}— 2]grid/metallocyclic architecture (see picture).",

author = "Feng Li and Clegg, \{Jack K.\} and Laurence Goux-Capes and Guillaume Chastanet and D'Alessandro, \{Deanna M.\} and Jean-Fran{\c c}ois L{\'e}tard and Kepert, \{Cameron J.\}",

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volume = "50",

pages = "2820--2823",

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T1 - A mixed-spin molecular square with a hybrid [2Ã— 2]grid/metallocyclic architecture

AU - Li, Feng

AU - Clegg, Jack K.

AU - Goux-Capes, Laurence

AU - Chastanet, Guillaume

AU - D'Alessandro, Deanna M.

AU - Létard, Jean-François

AU - Kepert, Cameron J.

PY - 2011

Y1 - 2011

N2 - Hunting high and low: A cyanide-bridged rhombic mixed-spin Fe II-FeII complex that features low-spin (LS) and high-spin (HS) FeII centers was prepared by self-assembly including the decomposition of SeCN. The structural motif represents a hybrid [2Ã— 2]grid/metallocyclic architecture (see picture).

AB - Hunting high and low: A cyanide-bridged rhombic mixed-spin Fe II-FeII complex that features low-spin (LS) and high-spin (HS) FeII centers was prepared by self-assembly including the decomposition of SeCN. The structural motif represents a hybrid [2Ã— 2]grid/metallocyclic architecture (see picture).

UR - http://hdl.handle.net/1959.7/uws:25920

U2 - 10.1002/anie.201007409

DO - 10.1002/anie.201007409

M3 - Article

SN - 1433-7851

VL - 50

SP - 2820

EP - 2823

JO - Angewandte Chemie (International Edition)

JF - Angewandte Chemie (International Edition)

IS - 12

ER -

A mixed-spin molecular square with a hybrid [2Ã— 2]grid/metallocyclic architecture

Abstract

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