A mixed-spin molecular square with a hybrid [2× 2]grid/metallocyclic architecture

Feng Li, Jack K. Clegg, Laurence Goux-Capes, Guillaume Chastanet, Deanna M. D'Alessandro, Jean-François Létard, Cameron J. Kepert

Research output: Contribution to journalArticlepeer-review

41 Citations (Scopus)

Abstract

Hunting high and low: A cyanide-bridged rhombic mixed-spin Fe II-FeII complex that features low-spin (LS) and high-spin (HS) FeII centers was prepared by self-assembly including the decomposition of SeCN. The structural motif represents a hybrid [2× 2]grid/metallocyclic architecture (see picture).
Original languageEnglish
Pages (from-to)2820-2823
Number of pages4
JournalAngewandte Chemie (International Edition)
Volume50
Issue number12
DOIs
Publication statusPublished - 2011

Cite this