A mixed-spin spin-crossover thiozolylimine [Fe4L6]8+ cage

Li Li; Alexander R. Craze; Outi Mustonen; Hikaru Zenno; Jacob J. Whittaker; Shinya Hayami; Leonard F. Lindoy; Christopher E. Marjo; Jack K. Clegg; Janice R. Aldrich-Wright; Feng Li

doi:10.1039/C9DT01947B

A mixed-spin spin-crossover thiozolylimine [Fe4L6]8+ cage

Li Li
, Alexander R. Craze
, Outi Mustonen
, Hikaru Zenno
, Jacob J. Whittaker
, Shinya Hayami
, Leonard F. Lindoy
, Christopher E. Marjo
, Jack K. Clegg
, Janice R. Aldrich-Wright
, Feng Li

Sch Hlth Sci
University of New South Wales
Kumamoto University
University of Queensland
The University of Sydney

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

The self-assembly of a mixed-spin [Fe4L6](8+) tetrahedral cage is reported. The cage undergoes temperature induced spin-crossover with a 29 K hystereisis. Variable temperature X-ray photoelectron spectroscopy (VT-XPS), combined with SQUID data, allowed differentiation between the surface and bulk magnetic properties.

Original language	English
Pages (from-to)	9935-9938
Number of pages	4
Journal	Dalton Transactions
Volume	48
Issue number	27
DOIs	https://doi.org/10.1039/C9DT01947B https://doi.org/10.1039/c9dt01947b
Publication status	Published - 2019

Keywords

chemistry
self-assembly (chemistry)

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title = "A mixed-spin spin-crossover thiozolylimine [Fe4L6]8+ cage",

abstract = "The self-assembly of a mixed-spin [Fe4L6](8+) tetrahedral cage is reported. The cage undergoes temperature induced spin-crossover with a 29 K hystereisis. Variable temperature X-ray photoelectron spectroscopy (VT-XPS), combined with SQUID data, allowed differentiation between the surface and bulk magnetic properties.",

keywords = "chemistry, self-assembly (chemistry)",

author = "Li Li and Craze, \{Alexander R.\} and Outi Mustonen and Hikaru Zenno and Whittaker, \{Jacob J.\} and Shinya Hayami and Lindoy, \{Leonard F.\} and Marjo, \{Christopher E.\} and Clegg, \{Jack K.\} and Aldrich-Wright, \{Janice R.\} and Feng Li",

year = "2019",

doi = "10.1039/C9DT01947B",

language = "English",

volume = "48",

pages = "9935--9938",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "27",

}

TY - JOUR

T1 - A mixed-spin spin-crossover thiozolylimine [Fe4L6]8+ cage

AU - Li, Li

AU - Craze, Alexander R.

AU - Mustonen, Outi

AU - Zenno, Hikaru

AU - Whittaker, Jacob J.

AU - Hayami, Shinya

AU - Lindoy, Leonard F.

AU - Marjo, Christopher E.

AU - Clegg, Jack K.

AU - Aldrich-Wright, Janice R.

AU - Li, Feng

PY - 2019

Y1 - 2019

N2 - The self-assembly of a mixed-spin [Fe4L6](8+) tetrahedral cage is reported. The cage undergoes temperature induced spin-crossover with a 29 K hystereisis. Variable temperature X-ray photoelectron spectroscopy (VT-XPS), combined with SQUID data, allowed differentiation between the surface and bulk magnetic properties.

AB - The self-assembly of a mixed-spin [Fe4L6](8+) tetrahedral cage is reported. The cage undergoes temperature induced spin-crossover with a 29 K hystereisis. Variable temperature X-ray photoelectron spectroscopy (VT-XPS), combined with SQUID data, allowed differentiation between the surface and bulk magnetic properties.

KW - chemistry

KW - self-assembly (chemistry)

UR - http://handle.westernsydney.edu.au:8081/1959.7/uws:51741

U2 - 10.1039/C9DT01947B

DO - 10.1039/C9DT01947B

M3 - Article

C2 - 31197300

SN - 1477-9226

VL - 48

SP - 9935

EP - 9938

JO - Dalton Transactions

JF - Dalton Transactions

IS - 27

ER -

A mixed-spin spin-crossover thiozolylimine [Fe4L6]8+ cage

Abstract

Keywords

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