A two-component post-column derivatisation method utilising reaction flow chromatography

M. Selim; A. Soliven; M. Camenzuli; G. R. Dennis; H. J. Ritchie; R. A. Shalliker

doi:10.1016/j.microc.2014.04.005

A two-component post-column derivatisation method utilising reaction flow chromatography

M. Selim, A. Soliven, M. Camenzuli, G. R. Dennis, H. J. Ritchie, R. A. Shalliker

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

"Reaction flow (RF) chromatography" has recently emerged from exploiting a new column "Parallel Segmented Flow" (PSF) to post-column derivatisation (PCD) methods [1]. The main advantage RF has over conventional PCD methods is the elimination of large volume reaction coils, as mixing occurs in the PSF column outlet fitting design, therefore minimising peak broadening. In this investigation we take an existing PCD method for the detection of phenols and apply it to RF. The detection sensitivity of the RF method is discussed, with the results demonstrating that through careful control of the mobile phase and derivatisation reagent conditions the selectivity of the PCD reaction may target compounds other than phenols.

Original language	English
Pages (from-to)	87-91
Number of pages	5
Journal	Microchemical Journal
Volume	116
DOIs	https://doi.org/10.1016/j.microc.2014.04.005
Publication status	Published - 2014

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10.1016/j.microc.2014.04.005

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abstract = "{"}Reaction flow (RF) chromatography{"} has recently emerged from exploiting a new column {"}Parallel Segmented Flow{"} (PSF) to post-column derivatisation (PCD) methods [1]. The main advantage RF has over conventional PCD methods is the elimination of large volume reaction coils, as mixing occurs in the PSF column outlet fitting design, therefore minimising peak broadening. In this investigation we take an existing PCD method for the detection of phenols and apply it to RF. The detection sensitivity of the RF method is discussed, with the results demonstrating that through careful control of the mobile phase and derivatisation reagent conditions the selectivity of the PCD reaction may target compounds other than phenols.",

author = "M. Selim and A. Soliven and M. Camenzuli and Dennis, {G. R.} and Ritchie, {H. J.} and Shalliker, {R. A.}",

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T1 - A two-component post-column derivatisation method utilising reaction flow chromatography

AU - Selim, M.

AU - Soliven, A.

AU - Camenzuli, M.

AU - Dennis, G. R.

AU - Ritchie, H. J.

AU - Shalliker, R. A.

PY - 2014

Y1 - 2014

N2 - "Reaction flow (RF) chromatography" has recently emerged from exploiting a new column "Parallel Segmented Flow" (PSF) to post-column derivatisation (PCD) methods [1]. The main advantage RF has over conventional PCD methods is the elimination of large volume reaction coils, as mixing occurs in the PSF column outlet fitting design, therefore minimising peak broadening. In this investigation we take an existing PCD method for the detection of phenols and apply it to RF. The detection sensitivity of the RF method is discussed, with the results demonstrating that through careful control of the mobile phase and derivatisation reagent conditions the selectivity of the PCD reaction may target compounds other than phenols.

AB - "Reaction flow (RF) chromatography" has recently emerged from exploiting a new column "Parallel Segmented Flow" (PSF) to post-column derivatisation (PCD) methods [1]. The main advantage RF has over conventional PCD methods is the elimination of large volume reaction coils, as mixing occurs in the PSF column outlet fitting design, therefore minimising peak broadening. In this investigation we take an existing PCD method for the detection of phenols and apply it to RF. The detection sensitivity of the RF method is discussed, with the results demonstrating that through careful control of the mobile phase and derivatisation reagent conditions the selectivity of the PCD reaction may target compounds other than phenols.

UR - http://handle.uws.edu.au:8081/1959.7/548012

U2 - 10.1016/j.microc.2014.04.005

DO - 10.1016/j.microc.2014.04.005

M3 - Article

SN - 0026-265X

VL - 116

SP - 87

EP - 91

JO - Microchemical Journal

JF - Microchemical Journal

ER -

A two-component post-column derivatisation method utilising reaction flow chromatography

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