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Analytical derivatization techniques

  • Andrew Jones
  • , Agustín Acquaviva
  • , Julian Resch
  • , Arianne Soliven

Research output: Chapter in Book / Conference PaperChapterpeer-review

1 Citation (Scopus)

Abstract

The previous edition's chapter was a comprehensive and detailed outline of derivatization analytical techniques, that has been updated with a stronger emphasis on recent literature. The two main methods to incorporate a derivatization step in the analytical workflow are: (1) before/pre-column separation or (2) after/post-column separation. Derivatization has several advantages with enhancing the detection selectivity and sensitivity of specific compounds/groups of compounds that are present in your injected sample. This chapter includes a focus on GC, LC, methods, quantitation, specific applications and an additional section focused on recently designed column technologies for HPLC post-column derivatizations.

Original languageEnglish
Title of host publicationComprehensive Sampling and Sample Preparation
EditorsMustafa Soylak
PublisherAcademic Press
Chapter28
Pages649-690
Volume2
Edition2nd
ISBN (Electronic)9780443159794
ISBN (Print)9780443159787
DOIs
Publication statusPublished - 2025

Keywords

  • Acylation
  • Alkylation
  • Analytical derivatization techniques
  • Derivatization reagents
  • ECD
  • Esterification
  • GC/MS
  • HPLC
  • Sample handling and conditions
  • Silylation

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