Catalytic hydroarylation of alkynes with arenes in the presence of FeCl3 and AgOTf

Takuya Hashimoto; Shahajahan Kutubi; Takayuki Izumi; Ataur Rahman; Tsugio Kitamura

doi:10.1016/j.jorganchem.2010.08.009

Catalytic hydroarylation of alkynes with arenes in the presence of FeCl3 and AgOTf

Takuya Hashimoto, Shahajahan Kutubi, Takayuki Izumi, Ataur Rahman, Tsugio Kitamura

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

Hydroarylation of propiolic acids with various arenes in TFA proceeded efficiently in the presence of FeCl3/AgOTf catalyst system. In the case of electron-rich arenes, the iron-catalyzed hydroarylation gave cinnamic acids in moderate to high yields. The hydroarylation of phenylacetylene was observed but the catalyst was not effective under the same conditions.

Original language	English
Pages (from-to)	99-105
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	696
Issue number	1
DOIs	https://doi.org/10.1016/j.jorganchem.2010.08.009
Publication status	Published - 2011

Keywords

alkynes
aromatic compounds
cinnamates
hydrocarbons
iron catalysts

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10.1016/j.jorganchem.2010.08.009

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title = "Catalytic hydroarylation of alkynes with arenes in the presence of FeCl3 and AgOTf",

abstract = "Hydroarylation of propiolic acids with various arenes in TFA proceeded efficiently in the presence of FeCl3/AgOTf catalyst system. In the case of electron-rich arenes, the iron-catalyzed hydroarylation gave cinnamic acids in moderate to high yields. The hydroarylation of phenylacetylene was observed but the catalyst was not effective under the same conditions.",

keywords = "alkynes, aromatic compounds, cinnamates, hydrocarbons, iron catalysts",

author = "Takuya Hashimoto and Shahajahan Kutubi and Takayuki Izumi and Ataur Rahman and Tsugio Kitamura",

year = "2011",

doi = "10.1016/j.jorganchem.2010.08.009",

language = "English",

volume = "696",

pages = "99--105",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

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TY - JOUR

T1 - Catalytic hydroarylation of alkynes with arenes in the presence of FeCl3 and AgOTf

AU - Hashimoto, Takuya

AU - Kutubi, Shahajahan

AU - Izumi, Takayuki

AU - Rahman, Ataur

AU - Kitamura, Tsugio

PY - 2011

Y1 - 2011

N2 - Hydroarylation of propiolic acids with various arenes in TFA proceeded efficiently in the presence of FeCl3/AgOTf catalyst system. In the case of electron-rich arenes, the iron-catalyzed hydroarylation gave cinnamic acids in moderate to high yields. The hydroarylation of phenylacetylene was observed but the catalyst was not effective under the same conditions.

AB - Hydroarylation of propiolic acids with various arenes in TFA proceeded efficiently in the presence of FeCl3/AgOTf catalyst system. In the case of electron-rich arenes, the iron-catalyzed hydroarylation gave cinnamic acids in moderate to high yields. The hydroarylation of phenylacetylene was observed but the catalyst was not effective under the same conditions.

KW - alkynes

KW - aromatic compounds

KW - cinnamates

KW - hydrocarbons

KW - iron catalysts

UR - https://hdl.handle.net/1959.7/uws:57352

U2 - 10.1016/j.jorganchem.2010.08.009

DO - 10.1016/j.jorganchem.2010.08.009

M3 - Article

SN - 0022-328X

VL - 696

SP - 99

EP - 105

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

Catalytic hydroarylation of alkynes with arenes in the presence of FeCl3 and AgOTf

Abstract

Keywords

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