Characteristics of arsenic adsorption to sorghum biomass

  • M. N. Haque
  • , G. M. Morrison
  • , G. Perrusquía
  • , M. Gutierréz
  • , A. F. Aguilera
  • , I. Cano-Aguilera
  • , J. L. Gardea-Torresdey

Research output: Contribution to journalArticlepeer-review

84 Citations (Scopus)

Abstract

The development of efficient and economic new adsorbent materials for the removal of arsenic from groundwater is a priority in regions where human health is directly affected by elevated arsenic concentrations. Adsorption of arsenic on sorghum biomass (SB) was investigated for the removal of arsenic from aqueous solutions. Potentiometric titrations and FTIR analysis evidenced two potential binding sites associated with carboxyl and hydroxyl groups. Batch experiments were carried out to determine the equilibrium time for arsenic adsorption to SB. The effect of pH on arsenic adsorption to SB was investigated for a pH range of 2.0-10.0. A strong influence of pH was demonstrated with a maximum removal of arsenic at pH 5.0. Freundlich and Langmuir isotherms were applied to equilibrium data. The Freundlich model fitted the equilibrium data and provided evidence for site heterogeneity at the binding surface. Column experiments were performed to obtain the breakthrough curves for both non-immobilized sorghum biomass and immobilized sorghum biomass.

Original languageEnglish
Pages (from-to)30-35
Number of pages6
JournalJournal of Hazardous Materials
Volume145
Issue number1-2
DOIs
Publication statusPublished - 25 Jun 2007
Externally publishedYes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

  1. SDG 3 - Good Health and Well-being
    SDG 3 Good Health and Well-being
  2. SDG 6 - Clean Water and Sanitation
    SDG 6 Clean Water and Sanitation

Keywords

  • Adsorption
  • Binding sites
  • Equilibrium isotherms
  • pH
  • Sorghum biomass

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