TY - JOUR
T1 - Charge neutral [Cu2L2] and [Pd2L2] metallocycles : self-assembly, aggregation, and catalysis
AU - Kolodziejski, Michal
AU - Brock, Aidan J.
AU - Kurpik, Gracjan
AU - Walczak, Anna
AU - Li, Feng
AU - Clegg, Jack K.
AU - Stefankiewicz, Artur R.
N1 - Publisher Copyright:
© 2021 American Chemical Society.
PY - 2021/7/5
Y1 - 2021/7/5
N2 - A range of morphologically distinct metallosupramolecular Cu(II) and Pd(II) complexes has been constructed, based on the tritopic ligand 1,1′,1″-(benzene-1,3,5-triyl)tris(4,4-dimethylpentane-1,3-dione) (H3L). By control of the reaction conditions, it is possible to generate distinct coordination assemblies possessing either macrocyclic or polymeric structures and more importantly distinct activity in catalysis of the Suzuki-Miyaura cross-coupling.
AB - A range of morphologically distinct metallosupramolecular Cu(II) and Pd(II) complexes has been constructed, based on the tritopic ligand 1,1′,1″-(benzene-1,3,5-triyl)tris(4,4-dimethylpentane-1,3-dione) (H3L). By control of the reaction conditions, it is possible to generate distinct coordination assemblies possessing either macrocyclic or polymeric structures and more importantly distinct activity in catalysis of the Suzuki-Miyaura cross-coupling.
UR - http://hdl.handle.net/1959.7/uws:60054
U2 - 10.1021/acs.inorgchem.1c00967
DO - 10.1021/acs.inorgchem.1c00967
M3 - Article
C2 - 34114797
SN - 0020-1669
VL - 60
SP - 9673
EP - 9679
JO - Inorganic Chemistry
JF - Inorganic Chemistry
IS - 13
ER -