Conformational investigations on three large dinuclear triple helicates by single crystal X-ray diffraction

Kyle J. Howard-Smith; Matthew J. Wallis; James P. Flood; Hyunsung Min; Joseph C. Tadros; R. Tian; M. M. Bhadbhade; C. E. Marjo; Feng Li

doi:10.1007/s10847-024-01235-3

Conformational investigations on three large dinuclear triple helicates by single crystal X-ray diffraction

Kyle J. Howard-Smith, Matthew J. Wallis, James P. Flood, Hyunsung Min, Joseph C. Tadros, R. Tian, M. M. Bhadbhade, C. E. Marjo, Feng Li

Western Sydney University

Research output: Contribution to journal › Article › peer-review

Abstract

Three new dinuclear triple helicates were synthesised using a ditopic semi-rigid pyridylylimine ligand L, separated by a diphenoxy-biphenol spacer providing considerable length to the backbone. L and the new large dinuclear triple helicate complexes [Fe2L3](BF4)4 (1), [Ni2L3](BF4)4 (2) and [Zn2L3](BF4)4 (3) have been characterised in solution and solid state. Single crystal X-ray diffraction was used to investigate overall complex ion shape as the coordination sphere was modulated by metal ion selection. Small differences in complex shape were seen to arise due to subtle distortions in coordination sphere environments. This study sheds light on how the length and twist of dinuclear triple helicates can be tuned by selection of coordinating metal ion.

Original language	English
Pages (from-to)	199-207
Number of pages	9
Journal	Journal of Inclusion Phenomena and Macrocyclic Chemistry
Volume	104
Issue number	5-6
DOIs	https://doi.org/10.1007/s10847-024-01235-3
Publication status	Published - Jun 2024

Bibliographical note

Publisher Copyright:
© The Author(s) 2024.

Open Access - Access Right Statement

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article�s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article�s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons. org/licenses/by/4.0/.

Access to Document

10.1007/s10847-024-01235-3

Cite this

@article{7892d2f7a1d14cca9a3a423309da9580,

title = "Conformational investigations on three large dinuclear triple helicates by single crystal X-ray diffraction",

abstract = "Three new dinuclear triple helicates were synthesised using a ditopic semi-rigid pyridylylimine ligand L, separated by a diphenoxy-biphenol spacer providing considerable length to the backbone. L and the new large dinuclear triple helicate complexes [Fe2L3](BF4)4 (1), [Ni2L3](BF4)4 (2) and [Zn2L3](BF4)4 (3) have been characterised in solution and solid state. Single crystal X-ray diffraction was used to investigate overall complex ion shape as the coordination sphere was modulated by metal ion selection. Small differences in complex shape were seen to arise due to subtle distortions in coordination sphere environments. This study sheds light on how the length and twist of dinuclear triple helicates can be tuned by selection of coordinating metal ion.",

author = "Howard-Smith, {Kyle J.} and Wallis, {Matthew J.} and Flood, {James P.} and Hyunsung Min and Tadros, {Joseph C.} and R. Tian and Bhadbhade, {M. M.} and Marjo, {C. E.} and Feng Li",

note = "Publisher Copyright: {\textcopyright} The Author(s) 2024.",

year = "2024",

month = jun,

doi = "10.1007/s10847-024-01235-3",

language = "English",

volume = "104",

pages = "199--207",

journal = "Journal of Inclusion Phenomena and Macrocyclic Chemistry",

issn = "1388-3127",

publisher = "Springer Dordrecht",

number = "5-6",

}

TY - JOUR

T1 - Conformational investigations on three large dinuclear triple helicates by single crystal X-ray diffraction

AU - Howard-Smith, Kyle J.

AU - Wallis, Matthew J.

AU - Flood, James P.

AU - Min, Hyunsung

AU - Tadros, Joseph C.

AU - Tian, R.

AU - Bhadbhade, M. M.

AU - Marjo, C. E.

AU - Li, Feng

PY - 2024/6

Y1 - 2024/6

N2 - Three new dinuclear triple helicates were synthesised using a ditopic semi-rigid pyridylylimine ligand L, separated by a diphenoxy-biphenol spacer providing considerable length to the backbone. L and the new large dinuclear triple helicate complexes [Fe2L3](BF4)4 (1), [Ni2L3](BF4)4 (2) and [Zn2L3](BF4)4 (3) have been characterised in solution and solid state. Single crystal X-ray diffraction was used to investigate overall complex ion shape as the coordination sphere was modulated by metal ion selection. Small differences in complex shape were seen to arise due to subtle distortions in coordination sphere environments. This study sheds light on how the length and twist of dinuclear triple helicates can be tuned by selection of coordinating metal ion.

AB - Three new dinuclear triple helicates were synthesised using a ditopic semi-rigid pyridylylimine ligand L, separated by a diphenoxy-biphenol spacer providing considerable length to the backbone. L and the new large dinuclear triple helicate complexes [Fe2L3](BF4)4 (1), [Ni2L3](BF4)4 (2) and [Zn2L3](BF4)4 (3) have been characterised in solution and solid state. Single crystal X-ray diffraction was used to investigate overall complex ion shape as the coordination sphere was modulated by metal ion selection. Small differences in complex shape were seen to arise due to subtle distortions in coordination sphere environments. This study sheds light on how the length and twist of dinuclear triple helicates can be tuned by selection of coordinating metal ion.

UR - https://hdl.handle.net/1959.7/uws:77641

U2 - 10.1007/s10847-024-01235-3

DO - 10.1007/s10847-024-01235-3

M3 - Article

SN - 1388-3127

VL - 104

SP - 199

EP - 207

JO - Journal of Inclusion Phenomena and Macrocyclic Chemistry

JF - Journal of Inclusion Phenomena and Macrocyclic Chemistry

IS - 5-6

ER -

Conformational investigations on three large dinuclear triple helicates by single crystal X-ray diffraction

Abstract

Bibliographical note

Open Access - Access Right Statement

Access to Document

Other files and links

Fingerprint

Cite this