Corrosion of copper in distilled water without O2 and the detection of produced hydrogen

G. Hultquist; M. J. Graham; O. Kodra; S. Moisa; R. Liu; U. Bexell; J. L. Smialek

doi:10.1016/j.corsci.2015.03.009

Corrosion of copper in distilled water without O2 and the detection of produced hydrogen

G. Hultquist, M. J. Graham, O. Kodra, S. Moisa, R. Liu, U. Bexell, J. L. Smialek

Western Sydney University

Research output: Contribution to journal › Article › peer-review

Abstract

This paper reports on hydrogen pressures measured during 19,000 h immersion of copper in oxygenfree liquid distilled water. Copper corrosion products have been examined ex-situ by SEM and characterized by XPS and SIMS. XPS strongly indicates a corrosion product containing both oxygen and hydrogen. SIMS shows that oxygen is mainly present in the outer 0.3 lm surface region and that hydrogen penetrates to depths well below the corrosion product. Thermal desorption spectroscopy shows that the reaction product formed near room-temperature is less stable than that formed in air at 350 C.

Original language	English
Pages (from-to)	162-167
Number of pages	6
Journal	Corrosion Science
Volume	95
DOIs	https://doi.org/10.1016/j.corsci.2015.03.009
Publication status	Published - 2015

Keywords

copper
oxidation
x, ray photoelectron spectroscopy

Access to Document

10.1016/j.corsci.2015.03.009

Cite this

@article{8c7f633cb7fa4e7396f8b041fae7f5ec,

title = "Corrosion of copper in distilled water without O2 and the detection of produced hydrogen",

abstract = "This paper reports on hydrogen pressures measured during 19,000 h immersion of copper in oxygenfree liquid distilled water. Copper corrosion products have been examined ex-situ by SEM and characterized by XPS and SIMS. XPS strongly indicates a corrosion product containing both oxygen and hydrogen. SIMS shows that oxygen is mainly present in the outer 0.3 lm surface region and that hydrogen penetrates to depths well below the corrosion product. Thermal desorption spectroscopy shows that the reaction product formed near room-temperature is less stable than that formed in air at 350 C.",

keywords = "copper, oxidation, x, ray photoelectron spectroscopy",

author = "G. Hultquist and Graham, {M. J.} and O. Kodra and S. Moisa and R. Liu and U. Bexell and Smialek, {J. L.}",

year = "2015",

doi = "10.1016/j.corsci.2015.03.009",

language = "English",

volume = "95",

pages = "162--167",

journal = "Corrosion Science",

issn = "0010-938X",

publisher = "Elsevier",

}

TY - JOUR

T1 - Corrosion of copper in distilled water without O2 and the detection of produced hydrogen

AU - Hultquist, G.

AU - Graham, M. J.

AU - Kodra, O.

AU - Moisa, S.

AU - Liu, R.

AU - Bexell, U.

AU - Smialek, J. L.

PY - 2015

Y1 - 2015

N2 - This paper reports on hydrogen pressures measured during 19,000 h immersion of copper in oxygenfree liquid distilled water. Copper corrosion products have been examined ex-situ by SEM and characterized by XPS and SIMS. XPS strongly indicates a corrosion product containing both oxygen and hydrogen. SIMS shows that oxygen is mainly present in the outer 0.3 lm surface region and that hydrogen penetrates to depths well below the corrosion product. Thermal desorption spectroscopy shows that the reaction product formed near room-temperature is less stable than that formed in air at 350 C.

AB - This paper reports on hydrogen pressures measured during 19,000 h immersion of copper in oxygenfree liquid distilled water. Copper corrosion products have been examined ex-situ by SEM and characterized by XPS and SIMS. XPS strongly indicates a corrosion product containing both oxygen and hydrogen. SIMS shows that oxygen is mainly present in the outer 0.3 lm surface region and that hydrogen penetrates to depths well below the corrosion product. Thermal desorption spectroscopy shows that the reaction product formed near room-temperature is less stable than that formed in air at 350 C.

KW - copper

KW - oxidation

KW - x, ray photoelectron spectroscopy

UR - http://handle.uws.edu.au:8081/1959.7/uws:36045

U2 - 10.1016/j.corsci.2015.03.009

DO - 10.1016/j.corsci.2015.03.009

M3 - Article

SN - 0010-938X

VL - 95

SP - 162

EP - 167

JO - Corrosion Science

JF - Corrosion Science

ER -

Corrosion of copper in distilled water without O2 and the detection of produced hydrogen

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this