Defects engineering induced ultrahigh magnetization in rare earth element Nd‐doped MoS2

Xiang Ding, Xiangyuan Cui, Ahmed Sohail, Peter P. Murmu, John Kennedy, Nina Bao, Jun Ding, Rong Liu, Mingli Peng, Lan Wang, Xueze Chu, Ajayan Vinu, Simon P. Ringer, Jiabao Yi

Research output: Contribution to journalArticlepeer-review

Abstract

Various concentrations (0, 0.5, 1, and 5 at%) of Nd are doped into MoS2 single crystals via ion implantation. Experimental results reveal that Nd exists in the form of trivalent state when the doping concentration is below 5 at% and a variety of defects, such as sulfur and molybdenum vacancies, are formed in Nd-doped MoS2. Compared to pure MoS2 that only shows diamagnetism, Nd doping successfully induces room-temperature ferromagnetic ordering. Extremely high magnetization (1640 emu cm−3) is observed in 1 at% Nd-doped MoS2. First-principles density functional theory calculations suggest that the various structural defects, including substitutions, vacancies, interstitials, antisites, and their complexes, are magnetic possessing large spin moments. The defects coupled with Nd dopants ferromagnetically may form the bound magnetic polarons to induce ferromagnetic ordering. The work has demonstrated that through defects engineering and rare earth element doping, extremely high magnetization materials can be achieved in layered structured materials. On the other hand, though the experiment work is done by implanting MoS2 single crystals, theoretical calculations indicate that 2D MoS2 with bilayers or a few layers can also result in ultrahigh magnetization.
Original languageEnglish
Article number2000093
Number of pages9
JournalAdvanced Quantum Technologies
Volume4
Issue number2
DOIs
Publication statusPublished - 2021

Keywords

  • magnetization
  • molybdenum disulfide
  • rare earths
  • semiconductors

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