Displacement of norbornadiene (NBD) from PtR2(NBD) (R = Me, CF3) by weak ligands

Trevor G. Appleton; John R. Hall; Don W. Neale; Mark A. Williams

doi:10.1016/0022-328X(84)80669-5

Displacement of norbornadiene (NBD) from PtR₂(NBD) (R = Me, CF₃) by weak ligands

Trevor G. Appleton
, John R. Hall
, Don W. Neale
, Mark A. Williams

University of Queensland

Research output: Contribution to journal › Article › peer-review

41 Citations (Scopus)

Abstract

Norbornadiene (NBD) is more easily displaced from PtMe₂ (NBD) by other ligands than is cyclooctadiene (COD) from PtMe₂ (COD). cis-PtMe₂L₂ (L = py, 1 2tmen, 1 2en, NH₃, DMSO) have been prepared in this way. cis-PtMe₂py₂ is very reactive toward oxidative addition. Pyridine can usually be removed from the platinum(IV) products using acid. NBD is even more readily displaced from Pt(CF₃)₂ (NBD), giving cis-Pt(CF₃)₂L₂ (L = py, 1 2tmen, 1 2en, NH₃, DMSO, NCR, DMF, CN^-, I^-, acac^-). cis-Pt(CF₃)₂py₂ with CF₂I gives fac-Pt(CF₃)₃py₂I.

Original language	English
Pages (from-to)	c73-c76
Journal	Journal of Organometallic Chemistry
Volume	276
Issue number	3
DOIs	https://doi.org/10.1016/0022-328X(84)80669-5
Publication status	Published - 27 Nov 1984
Externally published	Yes

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@article{b636d6281b5a4fd785898f1f52d7de9c,

title = "Displacement of norbornadiene (NBD) from PtR2(NBD) (R = Me, CF3) by weak ligands",

abstract = "Norbornadiene (NBD) is more easily displaced from PtMe2 (NBD) by other ligands than is cyclooctadiene (COD) from PtMe2 (COD). cis-PtMe2L2 (L = py, 1 2tmen, 1 2en, NH3, DMSO) have been prepared in this way. cis-PtMe2py2 is very reactive toward oxidative addition. Pyridine can usually be removed from the platinum(IV) products using acid. NBD is even more readily displaced from Pt(CF3)2 (NBD), giving cis-Pt(CF3)2L2 (L = py, 1 2tmen, 1 2en, NH3, DMSO, NCR, DMF, CN-, I-, acac-). cis-Pt(CF3)2py2 with CF2I gives fac-Pt(CF3)3py2I.",

author = "Appleton, \{Trevor G.\} and Hall, \{John R.\} and Neale, \{Don W.\} and Williams, \{Mark A.\}",

year = "1984",

month = nov,

day = "27",

doi = "10.1016/0022-328X(84)80669-5",

language = "English",

volume = "276",

pages = "c73--c76",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "3",

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TY - JOUR

T1 - Displacement of norbornadiene (NBD) from PtR2(NBD) (R = Me, CF3) by weak ligands

AU - Appleton, Trevor G.

AU - Hall, John R.

AU - Neale, Don W.

AU - Williams, Mark A.

PY - 1984/11/27

Y1 - 1984/11/27

N2 - Norbornadiene (NBD) is more easily displaced from PtMe2 (NBD) by other ligands than is cyclooctadiene (COD) from PtMe2 (COD). cis-PtMe2L2 (L = py, 1 2tmen, 1 2en, NH3, DMSO) have been prepared in this way. cis-PtMe2py2 is very reactive toward oxidative addition. Pyridine can usually be removed from the platinum(IV) products using acid. NBD is even more readily displaced from Pt(CF3)2 (NBD), giving cis-Pt(CF3)2L2 (L = py, 1 2tmen, 1 2en, NH3, DMSO, NCR, DMF, CN-, I-, acac-). cis-Pt(CF3)2py2 with CF2I gives fac-Pt(CF3)3py2I.

AB - Norbornadiene (NBD) is more easily displaced from PtMe2 (NBD) by other ligands than is cyclooctadiene (COD) from PtMe2 (COD). cis-PtMe2L2 (L = py, 1 2tmen, 1 2en, NH3, DMSO) have been prepared in this way. cis-PtMe2py2 is very reactive toward oxidative addition. Pyridine can usually be removed from the platinum(IV) products using acid. NBD is even more readily displaced from Pt(CF3)2 (NBD), giving cis-Pt(CF3)2L2 (L = py, 1 2tmen, 1 2en, NH3, DMSO, NCR, DMF, CN-, I-, acac-). cis-Pt(CF3)2py2 with CF2I gives fac-Pt(CF3)3py2I.

UR - https://www.scopus.com/pages/publications/0003017062

U2 - 10.1016/0022-328X(84)80669-5

DO - 10.1016/0022-328X(84)80669-5

M3 - Article

AN - SCOPUS:0003017062

SN - 0022-328X

VL - 276

SP - c73-c76

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 3

ER -

Displacement of norbornadiene (NBD) from PtR₂(NBD) (R = Me, CF₃) by weak ligands

Abstract

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