Effect of poling time on filtration properties of PVDF membranes treated in intense electric fields

M. T. Darestani, T. C. Chilcott, H. G. L. Coster

Research output: Contribution to journalArticlepeer-review

12 Citations (Scopus)

Abstract

It was found that treatment in intense electric fields (i.e., electrical poling) changed the microstructure and filtration performance of polyvinylidene fluoride (PVDF) microfiltration membranes. The effect of temperature, sample size and time on the electrical breakdown of membranes was studied. It was shown that the hydraulic permeability and flux of the membranes can be tuned by changing the poling time. The effect of electrical poling on rejection and molecular weight cutoff was more significant. It was also found that the electrical breakdown of PVDF membranes is a gradual process and a long exposure time to an intense electric field can have adverse effects on the separation performance of the membranes.
Original languageEnglish
Pages (from-to)951-964
Number of pages14
JournalPolymer Bulletin
Volume71
Issue number4
DOIs
Publication statusPublished - 2014

Keywords

  • electric fields
  • fluorine compounds
  • microstructure

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