Electrochemically synthesized tin selenide thin films as efficient electrocatalyst for overall water splitting

Suman S. Kahandal; Poonam S. Sanap; Vinod V. Patil; Hansol Kim; Guanghai Piao; Suraj A. Khalate; Zafar Said; Umakant M. Patil; Anuradha C. Pawar; Balasaheb P. Pagar; Ji Man Kim; Ravindra N. Bulakhe

doi:10.1016/j.ijhydene.2024.02.250

Electrochemically synthesized tin selenide thin films as efficient electrocatalyst for overall water splitting

Suman S. Kahandal, Poonam S. Sanap, Vinod V. Patil, Hansol Kim, Guanghai Piao, Suraj A. Khalate, Zafar Said, Umakant M. Patil, Anuradha C. Pawar, Balasaheb P. Pagar, Ji Man Kim, Ravindra N. Bulakhe

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The objective of this study was to report electrocatalytic activity of tin selenide (SnSe) for oxygen evolution process (OER) and hydrogen evolution reaction (HER). Simple and inexpensive SnSe thin films were deposited onto a steel substrate using an electrodeposition method. Orthorhombic SnSe required a low overpotential value of 325, 317, 314 mV for OER and a low overpotential value of 273, 219, 194 mV for HER for SnSe-1, SnSe-2, and SnSe-3 electrodes, respectively, to reach a current density of 10 mA/cm2. The thickness of thin film increased over time 50, 60, and 70 min for each successive SnSe-1 to SnSe-3 samples. SEM image indicated crystalline in nature with compact grain-like morphology on the entire surface of the substrate. The SnSe-3 sample displayed low Tafel slopes of 90 and 68 mV/dec for OER and HER, respectively. EDX showed that atomic percentage ratio of Sn: Se was 54:46 for SnSe-3 thin film. Overall results suggest that electrochemically synthesized SnSe is a promising candidate as an efficient electrocatalyst for overall water splitting.

Original language	English
Pages (from-to)	710-720
Number of pages	11
Journal	International Journal of Hydrogen Energy
Volume	61
DOIs	https://doi.org/10.1016/j.ijhydene.2024.02.250
Publication status	Published - 3 Apr 2024
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2024 Hydrogen Energy Publications LLC

Keywords

Electrocatalyst
HER
OER
Overpotential
Tin selenide
Water splitting

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.ijhydene.2024.02.250

Cite this

Kahandal, S. S., Sanap, P. S., Patil, V. V., Kim, H., Piao, G., Khalate, S. A., Said, Z., Patil, U. M., Pawar, A. C., Pagar, B. P., Kim, J. M., & Bulakhe, R. N. (2024). Electrochemically synthesized tin selenide thin films as efficient electrocatalyst for overall water splitting. International Journal of Hydrogen Energy, 61, 710-720. https://doi.org/10.1016/j.ijhydene.2024.02.250

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title = "Electrochemically synthesized tin selenide thin films as efficient electrocatalyst for overall water splitting",

abstract = "The objective of this study was to report electrocatalytic activity of tin selenide (SnSe) for oxygen evolution process (OER) and hydrogen evolution reaction (HER). Simple and inexpensive SnSe thin films were deposited onto a steel substrate using an electrodeposition method. Orthorhombic SnSe required a low overpotential value of 325, 317, 314 mV for OER and a low overpotential value of 273, 219, 194 mV for HER for SnSe-1, SnSe-2, and SnSe-3 electrodes, respectively, to reach a current density of 10 mA/cm2. The thickness of thin film increased over time 50, 60, and 70 min for each successive SnSe-1 to SnSe-3 samples. SEM image indicated crystalline in nature with compact grain-like morphology on the entire surface of the substrate. The SnSe-3 sample displayed low Tafel slopes of 90 and 68 mV/dec for OER and HER, respectively. EDX showed that atomic percentage ratio of Sn: Se was 54:46 for SnSe-3 thin film. Overall results suggest that electrochemically synthesized SnSe is a promising candidate as an efficient electrocatalyst for overall water splitting.",

keywords = "Electrocatalyst, HER, OER, Overpotential, Tin selenide, Water splitting",

author = "Kahandal, {Suman S.} and Sanap, {Poonam S.} and Patil, {Vinod V.} and Hansol Kim and Guanghai Piao and Khalate, {Suraj A.} and Zafar Said and Patil, {Umakant M.} and Pawar, {Anuradha C.} and Pagar, {Balasaheb P.} and Kim, {Ji Man} and Bulakhe, {Ravindra N.}",

note = "Publisher Copyright: {\textcopyright} 2024 Hydrogen Energy Publications LLC",

year = "2024",

month = apr,

day = "3",

doi = "10.1016/j.ijhydene.2024.02.250",

language = "English",

volume = "61",

pages = "710--720",

journal = "International Journal of Hydrogen Energy",

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T1 - Electrochemically synthesized tin selenide thin films as efficient electrocatalyst for overall water splitting

AU - Kahandal, Suman S.

AU - Sanap, Poonam S.

AU - Patil, Vinod V.

AU - Kim, Hansol

AU - Piao, Guanghai

AU - Khalate, Suraj A.

AU - Said, Zafar

AU - Patil, Umakant M.

AU - Pawar, Anuradha C.

AU - Pagar, Balasaheb P.

AU - Kim, Ji Man

AU - Bulakhe, Ravindra N.

PY - 2024/4/3

Y1 - 2024/4/3

N2 - The objective of this study was to report electrocatalytic activity of tin selenide (SnSe) for oxygen evolution process (OER) and hydrogen evolution reaction (HER). Simple and inexpensive SnSe thin films were deposited onto a steel substrate using an electrodeposition method. Orthorhombic SnSe required a low overpotential value of 325, 317, 314 mV for OER and a low overpotential value of 273, 219, 194 mV for HER for SnSe-1, SnSe-2, and SnSe-3 electrodes, respectively, to reach a current density of 10 mA/cm2. The thickness of thin film increased over time 50, 60, and 70 min for each successive SnSe-1 to SnSe-3 samples. SEM image indicated crystalline in nature with compact grain-like morphology on the entire surface of the substrate. The SnSe-3 sample displayed low Tafel slopes of 90 and 68 mV/dec for OER and HER, respectively. EDX showed that atomic percentage ratio of Sn: Se was 54:46 for SnSe-3 thin film. Overall results suggest that electrochemically synthesized SnSe is a promising candidate as an efficient electrocatalyst for overall water splitting.

AB - The objective of this study was to report electrocatalytic activity of tin selenide (SnSe) for oxygen evolution process (OER) and hydrogen evolution reaction (HER). Simple and inexpensive SnSe thin films were deposited onto a steel substrate using an electrodeposition method. Orthorhombic SnSe required a low overpotential value of 325, 317, 314 mV for OER and a low overpotential value of 273, 219, 194 mV for HER for SnSe-1, SnSe-2, and SnSe-3 electrodes, respectively, to reach a current density of 10 mA/cm2. The thickness of thin film increased over time 50, 60, and 70 min for each successive SnSe-1 to SnSe-3 samples. SEM image indicated crystalline in nature with compact grain-like morphology on the entire surface of the substrate. The SnSe-3 sample displayed low Tafel slopes of 90 and 68 mV/dec for OER and HER, respectively. EDX showed that atomic percentage ratio of Sn: Se was 54:46 for SnSe-3 thin film. Overall results suggest that electrochemically synthesized SnSe is a promising candidate as an efficient electrocatalyst for overall water splitting.

KW - Electrocatalyst

KW - HER

KW - OER

KW - Overpotential

KW - Tin selenide

KW - Water splitting

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U2 - 10.1016/j.ijhydene.2024.02.250

DO - 10.1016/j.ijhydene.2024.02.250

M3 - Article

AN - SCOPUS:85186676876

SN - 0360-3199

VL - 61

SP - 710

EP - 720

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

ER -

Electrochemically synthesized tin selenide thin films as efficient electrocatalyst for overall water splitting

Abstract

Bibliographical note

Keywords

UN SDGs

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