High-resolution separation of oligo(acrylic acid) by capillary zone electrophoresis

Patrice Castignolles; Marianne Gaborieau; Emily F. Hilder; Ewan Sprong; Christopher J. Ferguson; Robert G. Gilbert

doi:10.1002/marc.200500641

High-resolution separation of oligo(acrylic acid) by capillary zone electrophoresis

Patrice Castignolles, Marianne Gaborieau, Emily F. Hilder, Ewan Sprong, Christopher J. Ferguson, Robert G. Gilbert

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23 Citations (Scopus)

Abstract

Oligo(acrylic acid)s, produced by RAFT polymerization, have been separated and analyzed for the first time by capillary zone electrophoresis. The resolution obtained by capillary electrophoresis in borate buffers is far higher than that currently achieved using size exclusion chromatography. This work demonstrates that capillary electrophoresis is the technique of choice for the characterization of oligomers of acrylic acid and of other water-soluble monomers involved in emulsion polymerization processes.

Original language	English
Pages (from-to)	42-46
Number of pages	5
Journal	Macromolecular Rapid Communications
Volume	Vol. 27
Issue number	No. 1
DOIs	https://doi.org/10.1002/marc.200500641
Publication status	Published - 2006

Keywords

acrylates
capillary electrophoresis

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10.1002/marc.200500641

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abstract = "Oligo(acrylic acid)s, produced by RAFT polymerization, have been separated and analyzed for the first time by capillary zone electrophoresis. The resolution obtained by capillary electrophoresis in borate buffers is far higher than that currently achieved using size exclusion chromatography. This work demonstrates that capillary electrophoresis is the technique of choice for the characterization of oligomers of acrylic acid and of other water-soluble monomers involved in emulsion polymerization processes.",

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author = "Patrice Castignolles and Marianne Gaborieau and Hilder, {Emily F.} and Ewan Sprong and Ferguson, {Christopher J.} and Gilbert, {Robert G.}",

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T1 - High-resolution separation of oligo(acrylic acid) by capillary zone electrophoresis

AU - Castignolles, Patrice

AU - Gaborieau, Marianne

AU - Hilder, Emily F.

AU - Sprong, Ewan

AU - Ferguson, Christopher J.

AU - Gilbert, Robert G.

PY - 2006

Y1 - 2006

N2 - Oligo(acrylic acid)s, produced by RAFT polymerization, have been separated and analyzed for the first time by capillary zone electrophoresis. The resolution obtained by capillary electrophoresis in borate buffers is far higher than that currently achieved using size exclusion chromatography. This work demonstrates that capillary electrophoresis is the technique of choice for the characterization of oligomers of acrylic acid and of other water-soluble monomers involved in emulsion polymerization processes.

AB - Oligo(acrylic acid)s, produced by RAFT polymerization, have been separated and analyzed for the first time by capillary zone electrophoresis. The resolution obtained by capillary electrophoresis in borate buffers is far higher than that currently achieved using size exclusion chromatography. This work demonstrates that capillary electrophoresis is the technique of choice for the characterization of oligomers of acrylic acid and of other water-soluble monomers involved in emulsion polymerization processes.

KW - acrylates

KW - capillary electrophoresis

UR - http://handle.uws.edu.au:8081/1959.7/504981

U2 - 10.1002/marc.200500641

DO - 10.1002/marc.200500641

M3 - Article

SN - 1022-1336

VL - Vol. 27

SP - 42

EP - 46

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

IS - No. 1

ER -

High-resolution separation of oligo(acrylic acid) by capillary zone electrophoresis

Abstract

Keywords

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