In the limelight: 2D and 3D materials via photo-controlled radical polymerization

Reversible deactivation radical polymerization (RDRP), commonly referred to as controlled/living radical polymerization, has become an exceptionally useful method for synthesizing 2D and 3D materials. More recently, light has been used to regulate RDRP, which has provided inherent advantages compared with traditional approaches. Herein, we present some chemical mechanisms for photoRDRP and highlight the exceptional benefits that accompany the use of light to mediate RDRP processes. The application of photoRDRP for the synthesis of functional 2D and 3D materials fully exploits these benefits and can allow additional opportunities for advanced material synthesis. Outstanding systems that typify the use of photoRDRP in the synthesis of 2D and 3D materials are presented.