Investigation on the mathematical models of chloride diffusion coefficient in concrete exposed to marine environment

![CDATA[Degradation of reinforced concrete (RC) in maritime structures has become a worldwide problem due to its excessive costs of maintenance, repair, and replacement in addition to its environmental impacts and safety issues. Degradation of both concrete and steel which is the main reason of reduction in the service life of RC structures strongly depends on the diffusion process of moisture and aggressive species. In this paper, the major and popular mathematical models of diffusion process in concrete are surveyed and investigated. Predominantly in these models, the coefficient of chloride diffusion into the concrete is assumed to be constant. Whereas, experimental records indicate that diffusion coefficient is a function of time. Subsequently, data analysis and comparisons between the existing analytical models for predicting the diffusion coefficient with the existing experimental database are carried out in this study. Clearly, these comparisons reveal that there are gaps between the existing mathematical models and previously recorded experimental results. Perhaps, these gaps may be interpreted as influence of the other affecting parameters on the diffusion coefficient such as temperature, aggregate size and relative humidity in addition to the water cement ratio. Accordingly, the existing mathematical models are not adequate enough to predict the diffusion coefficient precisely and further studies need to be performed. At the present, an extensive experimental and analytical research in this regard is being conducted in the CBIR group, University of Technology Sydney.]]