Ionic conduction and self-diffusion near infinitesimal concentration in lithium salt-organic solvent electrolytes

Yuichi Aihara; Kyoko Sugimoto; William S. Price; Kikuko Hayamizu

doi:10.1063/1.482004

Ionic conduction and self-diffusion near infinitesimal concentration in lithium salt-organic solvent electrolytes

Yuichi Aihara
, Kyoko Sugimoto
, William S. Price
, Kikuko Hayamizu

Research output: Contribution to journal › Article › peer-review

109 Citations (Scopus)

Abstract

Self-diffusion measurements of the components of four binary organic electrolyte systems comprised of an organic solvent [γ-butyrolactone (GBL) or polypropylenecarbonate (PC)] and a (1:1) lithium salt (LiBF₄ or LiTFSI) were carried out. The four systems (GBL-LiBF₄, GBL-LiTFSI, PC-LiBF₄, and PC-LiTFSI) were studied from 0.5 M to extremely low dilutions. In addition to clarifying the conduction mechanisms in the extremely dilute region, a rational extension of the Debye-Huckel-Onsager equation was established.

Original language	English
Pages (from-to)	1981-1991
Number of pages	11
Journal	Journal of Chemical Physics
Volume	113
Issue number	5
DOIs	https://doi.org/10.1063/1.482004
Publication status	Published - Aug 2000
Externally published	Yes

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abstract = "Self-diffusion measurements of the components of four binary organic electrolyte systems comprised of an organic solvent [γ-butyrolactone (GBL) or polypropylenecarbonate (PC)] and a (1:1) lithium salt (LiBF4 or LiTFSI) were carried out. The four systems (GBL-LiBF4, GBL-LiTFSI, PC-LiBF4, and PC-LiTFSI) were studied from 0.5 M to extremely low dilutions. In addition to clarifying the conduction mechanisms in the extremely dilute region, a rational extension of the Debye-Huckel-Onsager equation was established.",

author = "Yuichi Aihara and Kyoko Sugimoto and Price, \{William S.\} and Kikuko Hayamizu",

year = "2000",

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AU - Hayamizu, Kikuko

PY - 2000/8

Y1 - 2000/8

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AB - Self-diffusion measurements of the components of four binary organic electrolyte systems comprised of an organic solvent [γ-butyrolactone (GBL) or polypropylenecarbonate (PC)] and a (1:1) lithium salt (LiBF4 or LiTFSI) were carried out. The four systems (GBL-LiBF4, GBL-LiTFSI, PC-LiBF4, and PC-LiTFSI) were studied from 0.5 M to extremely low dilutions. In addition to clarifying the conduction mechanisms in the extremely dilute region, a rational extension of the Debye-Huckel-Onsager equation was established.

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JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 5

ER -

Ionic conduction and self-diffusion near infinitesimal concentration in lithium salt-organic solvent electrolytes

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