Juniperolide A : a new polyketide isolated from a terrestrial actinomycete, Streptomyces sp.

Ritesh Raju, Oleksandr Gromyko, Viktor Fedorenko, Andriy Luzhetskyy, Alberto Plaza, Rolf Müller

    Research output: Contribution to journalArticlepeer-review

    14 Citations (Scopus)

    Abstract

    A new linear polyketide, juniperolide A (1), was produced by the terrestrial actinomycete (Lv1-48) isolated from the rhizosphere of the plant Juniperus excelsa. The juniperolide A (1) structure contains a THP unit and a 3-amino-2,3,6-trideoxyhexose as the glycosidic moiety. Mosher’s analysis was used for absolute stereochemistry determinations at C-2, C-8, C-20, and C-4′, while the relative stereochemistry assignments of the remaining stereocenters were based on ROESY correlations and J-based coupling.
    Original languageEnglish
    Pages (from-to)5860-5863
    Number of pages4
    JournalOrganic Letters
    Volume14
    Issue number23
    Publication statusPublished - 2012

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