TY - JOUR
T1 - Juniperolide A : a new polyketide isolated from a terrestrial actinomycete, Streptomyces sp.
AU - Raju, Ritesh
AU - Gromyko, Oleksandr
AU - Fedorenko, Viktor
AU - Luzhetskyy, Andriy
AU - Plaza, Alberto
AU - Müller, Rolf
PY - 2012
Y1 - 2012
N2 - A new linear polyketide, juniperolide A (1), was produced by the terrestrial actinomycete (Lv1-48) isolated from the rhizosphere of the plant Juniperus excelsa. The juniperolide A (1) structure contains a THP unit and a 3-amino-2,3,6-trideoxyhexose as the glycosidic moiety. Mosher's analysis was used for absolute stereochemistry determinations at C-2, C-8, C-20, and C-4"², while the relative stereochemistry assignments of the remaining stereocenters were based on ROESY correlations and J-based coupling.
AB - A new linear polyketide, juniperolide A (1), was produced by the terrestrial actinomycete (Lv1-48) isolated from the rhizosphere of the plant Juniperus excelsa. The juniperolide A (1) structure contains a THP unit and a 3-amino-2,3,6-trideoxyhexose as the glycosidic moiety. Mosher's analysis was used for absolute stereochemistry determinations at C-2, C-8, C-20, and C-4"², while the relative stereochemistry assignments of the remaining stereocenters were based on ROESY correlations and J-based coupling.
UR - http://handle.uws.edu.au:8081/1959.7/544886
UR - http://pubs.acs.org/doi/abs/10.1021/ol302766z
M3 - Article
C2 - 23170775
SN - 1523-7052
VL - 14
SP - 5860
EP - 5863
JO - Organic Letters
JF - Organic Letters
IS - 23
ER -