TY - JOUR
T1 - Nanoporous GeO 2 /Cu/Cu2O network synthesized by dealloying method for stable Li-ion storage
AU - Wang, Zhifeng
AU - Zhang, Xiaomin
AU - Yan, Yonghui
AU - Zhang, Yongguang
AU - Wang, Yichao
AU - Qin, Chunling
AU - Bakenov, Zhumabay
PY - 2019
Y1 - 2019
N2 - Transition metal oxide Cu 2 O anode is still not meeting the current market demands due to the low theoretical capacity and poor cycle stability. We herein report the synthesis of a nanoporous GeO 2 /Cu/Cu 2 O network by a straightforward dealloying method. The resulting material possesses high porosity which served to alleviate the stress incurred during lithiation/delithiation volume variation and presents good conductivity for fast electron transfer. Enhanced electrochemical performance is observed when measured as an anode material, delivering 715 mAh g −1 at 200 mA g −1 after 50 cycles and offered 504 mAh g −1 even at a high current density of 1600 mA g −1 after 150 cycles. Furthermore, the material also demonstrates excellent rate performance of 812, 782, 741, 695, 635 and 552 mAh g −1 at 100, 200, 500, 800, 1600 and 3200 mA g −1 current densities, respectively. The enhanced Li storage performances could be ascribed to the reticular ligament with high porosity, the increased conductivity by Cu as well as the improved capacity from GeO 2. Moreover, this work provides us a new material design strategy to fabricate various porous composite anodes with high capacity through a straightforward dealloying method in future for lithium-ion battery applications.
AB - Transition metal oxide Cu 2 O anode is still not meeting the current market demands due to the low theoretical capacity and poor cycle stability. We herein report the synthesis of a nanoporous GeO 2 /Cu/Cu 2 O network by a straightforward dealloying method. The resulting material possesses high porosity which served to alleviate the stress incurred during lithiation/delithiation volume variation and presents good conductivity for fast electron transfer. Enhanced electrochemical performance is observed when measured as an anode material, delivering 715 mAh g −1 at 200 mA g −1 after 50 cycles and offered 504 mAh g −1 even at a high current density of 1600 mA g −1 after 150 cycles. Furthermore, the material also demonstrates excellent rate performance of 812, 782, 741, 695, 635 and 552 mAh g −1 at 100, 200, 500, 800, 1600 and 3200 mA g −1 current densities, respectively. The enhanced Li storage performances could be ascribed to the reticular ligament with high porosity, the increased conductivity by Cu as well as the improved capacity from GeO 2. Moreover, this work provides us a new material design strategy to fabricate various porous composite anodes with high capacity through a straightforward dealloying method in future for lithium-ion battery applications.
UR - https://hdl.handle.net/1959.7/uws:71275
U2 - 10.1016/j.electacta.2019.01.127
DO - 10.1016/j.electacta.2019.01.127
M3 - Article
SN - 0013-4686
VL - 300
SP - 363
EP - 372
JO - Electrochimica Acta
JF - Electrochimica Acta
ER -