Neodymium coordination polymers with propionate, succinate and mixed succinate-oxalate ligands : synthesis, structures and spectroscopic characterization

Nicholas Scales; Yingjie Zhang; Mohan Bhadbhade; Inna Karatchevtseva; Linggen Kong; Gregory R. Lumpkin; Feng Li

doi:10.1016/j.poly.2015.07.065

Neodymium coordination polymers with propionate, succinate and mixed succinate-oxalate ligands : synthesis, structures and spectroscopic characterization

Nicholas Scales, Yingjie Zhang, Mohan Bhadbhade, Inna Karatchevtseva, Linggen Kong, Gregory R. Lumpkin, Feng Li

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Three neodymium (Nd) coordination polymers with propionate, succinate and mixed succinate-oxalate ligands have been synthesized and structurally characterized. Nd<inf>2</inf>(C<inf>3</inf>H<inf>5</inf>O<inf>2</inf>)<inf>6</inf>(H<inf>2</inf>O)<inf>3</inf>ÃÂ·3H<inf>2</inf>O (1) has a 1D polymeric structure built with both ninefold and ten-fold coordinated neodymium polyhedra linked through μ<inf>2</inf>-bridging propionate ligands. Nd<inf>2</inf>(C<inf>4</inf>H<inf>4</inf>O<inf>4</inf>)<inf>3</inf>(H<inf>2</inf>O)<inf>2</inf> (2) has a 3D polymeric structure constructed with two distinct ninefold coordinated neodymium polyhedra linked through three types of succinate ligands, two in μ<inf>4</inf>- and one in μ<inf>3</inf>-coordination modes. Nd<inf>2</inf>(C<inf>4</inf>H<inf>4</inf>O<inf>4</inf>)<inf>2</inf>(C<inf>2</inf>O<inf>4</inf>)(H<inf>2</inf>O)<inf>4</inf>ÃÂ·3H<inf>2</inf>O (3) is built with two types of ten-fold coordinated neodymium polyhedra linked through μ<inf>4</inf>-succinate ligands into 2D undulating layers which are further connected through μ<inf>2</inf>-oxalate ligands forming a 3D network with channels. Their vibrational modes and thermal stabilities have been further investigated.

Original language	English
Pages (from-to)	130-136
Number of pages	7
Journal	Polyhedron
Volume	102
DOIs	https://doi.org/10.1016/j.poly.2015.07.065
Publication status	Published - 2015

Keywords

coordination polymers
neodymium
oxalates
propionates
succinates

Access to Document

10.1016/j.poly.2015.07.065

http://ezproxy.uws.edu.au/login?url=http://doi.org/10.1016/j.poly.2015.07.065

Cite this

@article{321bc9fd5b664cf7ac77ba6f71c0e3b9,

title = "Neodymium coordination polymers with propionate, succinate and mixed succinate-oxalate ligands : synthesis, structures and spectroscopic characterization",

abstract = "Three neodymium (Nd) coordination polymers with propionate, succinate and mixed succinate-oxalate ligands have been synthesized and structurally characterized. Nd2(C3H5O2)6(H2O)3{\~A}{\^A}·3H2O (1) has a 1D polymeric structure built with both ninefold and ten-fold coordinated neodymium polyhedra linked through μ2-bridging propionate ligands. Nd2(C4H4O4)3(H2O)2 (2) has a 3D polymeric structure constructed with two distinct ninefold coordinated neodymium polyhedra linked through three types of succinate ligands, two in μ4- and one in μ3-coordination modes. Nd2(C4H4O4)2(C2O4)(H2O)4{\~A}{\^A}·3H2O (3) is built with two types of ten-fold coordinated neodymium polyhedra linked through μ4-succinate ligands into 2D undulating layers which are further connected through μ2-oxalate ligands forming a 3D network with channels. Their vibrational modes and thermal stabilities have been further investigated.",

keywords = "coordination polymers, neodymium, oxalates, propionates, succinates",

author = "Nicholas Scales and Yingjie Zhang and Mohan Bhadbhade and Inna Karatchevtseva and Linggen Kong and Lumpkin, {Gregory R.} and Feng Li",

year = "2015",

doi = "10.1016/j.poly.2015.07.065",

language = "English",

volume = "102",

pages = "130--136",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier",

}

TY - JOUR

T1 - Neodymium coordination polymers with propionate, succinate and mixed succinate-oxalate ligands : synthesis, structures and spectroscopic characterization

AU - Scales, Nicholas

AU - Zhang, Yingjie

AU - Bhadbhade, Mohan

AU - Karatchevtseva, Inna

AU - Kong, Linggen

AU - Lumpkin, Gregory R.

AU - Li, Feng

PY - 2015

Y1 - 2015

N2 - Three neodymium (Nd) coordination polymers with propionate, succinate and mixed succinate-oxalate ligands have been synthesized and structurally characterized. Nd2(C3H5O2)6(H2O)3ÃÂ·3H2O (1) has a 1D polymeric structure built with both ninefold and ten-fold coordinated neodymium polyhedra linked through μ2-bridging propionate ligands. Nd2(C4H4O4)3(H2O)2 (2) has a 3D polymeric structure constructed with two distinct ninefold coordinated neodymium polyhedra linked through three types of succinate ligands, two in μ4- and one in μ3-coordination modes. Nd2(C4H4O4)2(C2O4)(H2O)4ÃÂ·3H2O (3) is built with two types of ten-fold coordinated neodymium polyhedra linked through μ4-succinate ligands into 2D undulating layers which are further connected through μ2-oxalate ligands forming a 3D network with channels. Their vibrational modes and thermal stabilities have been further investigated.

AB - Three neodymium (Nd) coordination polymers with propionate, succinate and mixed succinate-oxalate ligands have been synthesized and structurally characterized. Nd2(C3H5O2)6(H2O)3ÃÂ·3H2O (1) has a 1D polymeric structure built with both ninefold and ten-fold coordinated neodymium polyhedra linked through μ2-bridging propionate ligands. Nd2(C4H4O4)3(H2O)2 (2) has a 3D polymeric structure constructed with two distinct ninefold coordinated neodymium polyhedra linked through three types of succinate ligands, two in μ4- and one in μ3-coordination modes. Nd2(C4H4O4)2(C2O4)(H2O)4ÃÂ·3H2O (3) is built with two types of ten-fold coordinated neodymium polyhedra linked through μ4-succinate ligands into 2D undulating layers which are further connected through μ2-oxalate ligands forming a 3D network with channels. Their vibrational modes and thermal stabilities have been further investigated.

KW - coordination polymers

KW - neodymium

KW - oxalates

KW - propionates

KW - succinates

UR - http://handle.uws.edu.au:8081/1959.7/uws:31913

U2 - 10.1016/j.poly.2015.07.065

DO - 10.1016/j.poly.2015.07.065

M3 - Article

SN - 0277-5387

VL - 102

SP - 130

EP - 136

JO - Polyhedron

JF - Polyhedron

ER -

Neodymium coordination polymers with propionate, succinate and mixed succinate-oxalate ligands : synthesis, structures and spectroscopic characterization

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this