TY - JOUR
T1 - On the mechanical properties of melt-blended nylon 6/ethylene-octene copolymer/graphene nanoplatelet nanocomposites
AU - Attar, Suhail
AU - Chen, Biqiong
AU - Cicala, Gianluca
AU - Catalanotti, Giuseppe
AU - Scalici, Tommasso
AU - Falzon, Brian G.
PY - 2022
Y1 - 2022
N2 - Ethylene-octene copolymer (EOC) with a loading level of 20 wt%, maleated EOC (EOC-g-MA) with a loading level of 3 wt% and graphene nanoplatelets (GnPs) at four different loading levels, i.e., 3 wt%, 5 wt%, 10 wt% and 15 wt% were added to nylon 6 to prepare nanocomposites using a twin-screw extruder with a high shear rate screw running at 300 rpm. Increased stiffness was observed with the addition of GnPs while tensile strength of nanocomposites was only slightly influenced. Addition of GnPs into nylon 6 and nylon 6/EOC blend caused either a reduction in the Charpy impact strength or it remained unaffected. Similarly, the Izod impact strength of compatibilized nylon 6/EOC blend increased while that of nylon 6/EOC blend-based nanocomposites decreased. An increase was observed in the compressive Izod impact strength of compatibilized nylon 6/EOC blend. Addition of GnPs to nylon 6/EOC blend caused an increase in the fracture toughness due to their influence on the morphology and fracture mechanisms. This study shows that simultaneous addition of high surface area GnPs and an impact modifier to neat nylon 6 can help achieve enhancement and tailoring of stiffness and toughness.
AB - Ethylene-octene copolymer (EOC) with a loading level of 20 wt%, maleated EOC (EOC-g-MA) with a loading level of 3 wt% and graphene nanoplatelets (GnPs) at four different loading levels, i.e., 3 wt%, 5 wt%, 10 wt% and 15 wt% were added to nylon 6 to prepare nanocomposites using a twin-screw extruder with a high shear rate screw running at 300 rpm. Increased stiffness was observed with the addition of GnPs while tensile strength of nanocomposites was only slightly influenced. Addition of GnPs into nylon 6 and nylon 6/EOC blend caused either a reduction in the Charpy impact strength or it remained unaffected. Similarly, the Izod impact strength of compatibilized nylon 6/EOC blend increased while that of nylon 6/EOC blend-based nanocomposites decreased. An increase was observed in the compressive Izod impact strength of compatibilized nylon 6/EOC blend. Addition of GnPs to nylon 6/EOC blend caused an increase in the fracture toughness due to their influence on the morphology and fracture mechanisms. This study shows that simultaneous addition of high surface area GnPs and an impact modifier to neat nylon 6 can help achieve enhancement and tailoring of stiffness and toughness.
UR - https://hdl.handle.net/1959.7/uws:75607
U2 - 10.1016/j.polymer.2022.124619
DO - 10.1016/j.polymer.2022.124619
M3 - Article
SN - 0032-3861
VL - 243
JO - Polymer
JF - Polymer
M1 - 124619
ER -