Predesigned hexanuclear CuII and CuII/NiII metallacycles featuring six-node metallacoronand structural motifs

Feng Li; Jack K. Clegg; Paul Jensen; Keith Fisher; Leonard F. Lindoy; George V. Meehan; Boujemaa Moubaraki; Keith S. Murray

doi:10.1002/anie.200903185

Predesigned hexanuclear CuII and CuII/NiII metallacycles featuring six-node metallacoronand structural motifs

Feng Li, Jack K. Clegg, Paul Jensen, Keith Fisher, Leonard F. Lindoy, George V. Meehan, Boujemaa Moubaraki, Keith S. Murray

School of Science

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

Crowning glory: The assembly of CuII or CuII and NiII and a new 1,4-aryl-linked bis(triketonato) ligand designed to adopt a bent configuration leads to unusual Cu6-nNinL 3 (n=0, 3) metallacycles that feature unique hexanuclear metallacoronand structural motifs. In the case of the hexanuclear Cu II species, strong antiferromagnetic interactions exist between proximate pairs of metal ions in each structure.

Original language	English
Pages (from-to)	7059-7063
Number of pages	5
Journal	Angewandte Chemie (International Edition)
Volume	48
Issue number	38
DOIs	https://doi.org/10.1002/anie.200903185
Publication status	Published - 2009

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10.1002/anie.200903185

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title = "Predesigned hexanuclear CuII and CuII/NiII metallacycles featuring six-node metallacoronand structural motifs",

abstract = "Crowning glory: The assembly of CuII or CuII and NiII and a new 1,4-aryl-linked bis(triketonato) ligand designed to adopt a bent configuration leads to unusual Cu6-nNinL 3 (n=0, 3) metallacycles that feature unique hexanuclear metallacoronand structural motifs. In the case of the hexanuclear Cu II species, strong antiferromagnetic interactions exist between proximate pairs of metal ions in each structure.",

author = "Feng Li and Clegg, {Jack K.} and Paul Jensen and Keith Fisher and Lindoy, {Leonard F.} and Meehan, {George V.} and Boujemaa Moubaraki and Murray, {Keith S.}",

year = "2009",

doi = "10.1002/anie.200903185",

language = "English",

volume = "48",

pages = "7059--7063",

journal = "Angewandte Chemie (International Edition)",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "38",

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T1 - Predesigned hexanuclear CuII and CuII/NiII metallacycles featuring six-node metallacoronand structural motifs

AU - Li, Feng

AU - Clegg, Jack K.

AU - Jensen, Paul

AU - Fisher, Keith

AU - Lindoy, Leonard F.

AU - Meehan, George V.

AU - Moubaraki, Boujemaa

AU - Murray, Keith S.

PY - 2009

Y1 - 2009

N2 - Crowning glory: The assembly of CuII or CuII and NiII and a new 1,4-aryl-linked bis(triketonato) ligand designed to adopt a bent configuration leads to unusual Cu6-nNinL 3 (n=0, 3) metallacycles that feature unique hexanuclear metallacoronand structural motifs. In the case of the hexanuclear Cu II species, strong antiferromagnetic interactions exist between proximate pairs of metal ions in each structure.

AB - Crowning glory: The assembly of CuII or CuII and NiII and a new 1,4-aryl-linked bis(triketonato) ligand designed to adopt a bent configuration leads to unusual Cu6-nNinL 3 (n=0, 3) metallacycles that feature unique hexanuclear metallacoronand structural motifs. In the case of the hexanuclear Cu II species, strong antiferromagnetic interactions exist between proximate pairs of metal ions in each structure.

UR - http://hdl.handle.net/1959.7/uws:24787

U2 - 10.1002/anie.200903185

DO - 10.1002/anie.200903185

M3 - Article

SN - 1433-7851

VL - 48

SP - 7059

EP - 7063

JO - Angewandte Chemie (International Edition)

JF - Angewandte Chemie (International Edition)

IS - 38

ER -

Predesigned hexanuclear CuII and CuII/NiII metallacycles featuring six-node metallacoronand structural motifs

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