Pyrolysis-GC-MS analysis of crude and heavy fuel oil asphaltenes for application in oil fingerprinting

Brenden J. Riley; Chris Lennard; Stephen Fuller; Val Spikmans

doi:10.1080/15275922.2017.1408163

Pyrolysis-GC-MS analysis of crude and heavy fuel oil asphaltenes for application in oil fingerprinting

Brenden J. Riley
, Chris Lennard
, Stephen Fuller
, Val Spikmans

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

A Pyrolysis" Gas Chromatography" Mass Spectrometry (Py-GC-MS) method was developed for the analysis and profiling of crude and heavy fuel oil asphaltenes, for application in oil fingerprinting. Asphaltenes were precipitated from ten geographically different oils using n-pentane, and analysed by Py-GC-MS. Alkane profiles and sulphur/aromatic profiles were used to compare the oils, and to correctly differentiate oils from different geographical regions. Py-GC-MS could not differentiate a weathered oil sample and a fresh oil sample from the same source. The results of this study support the findings from a previously developed FTIR method for asphaltene profiling.

Original language	English
Pages (from-to)	14-26
Number of pages	13
Journal	Environmental Forensics
Volume	19
Issue number	1
DOIs	https://doi.org/10.1080/15275922.2017.1408163
Publication status	Published - 2 Jan 2018

Bibliographical note

Publisher Copyright:
© 2018 Taylor & Francis.

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 14 Life Below Water

Keywords

alkanes
environmental forensics
oil spills
polycyclic aromatic hydrocarbons

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10.1080/15275922.2017.1408163

Cite this

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title = "Pyrolysis-GC-MS analysis of crude and heavy fuel oil asphaltenes for application in oil fingerprinting",

abstract = "A Pyrolysis{"} Gas Chromatography{"} Mass Spectrometry (Py-GC-MS) method was developed for the analysis and profiling of crude and heavy fuel oil asphaltenes, for application in oil fingerprinting. Asphaltenes were precipitated from ten geographically different oils using n-pentane, and analysed by Py-GC-MS. Alkane profiles and sulphur/aromatic profiles were used to compare the oils, and to correctly differentiate oils from different geographical regions. Py-GC-MS could not differentiate a weathered oil sample and a fresh oil sample from the same source. The results of this study support the findings from a previously developed FTIR method for asphaltene profiling.",

keywords = "alkanes, environmental forensics, oil spills, polycyclic aromatic hydrocarbons",

author = "Riley, \{Brenden J.\} and Chris Lennard and Stephen Fuller and Val Spikmans",

note = "Publisher Copyright: {\textcopyright} 2018 Taylor \& Francis.",

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doi = "10.1080/15275922.2017.1408163",

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T1 - Pyrolysis-GC-MS analysis of crude and heavy fuel oil asphaltenes for application in oil fingerprinting

AU - Riley, Brenden J.

AU - Lennard, Chris

AU - Fuller, Stephen

AU - Spikmans, Val

PY - 2018/1/2

Y1 - 2018/1/2

N2 - A Pyrolysis" Gas Chromatography" Mass Spectrometry (Py-GC-MS) method was developed for the analysis and profiling of crude and heavy fuel oil asphaltenes, for application in oil fingerprinting. Asphaltenes were precipitated from ten geographically different oils using n-pentane, and analysed by Py-GC-MS. Alkane profiles and sulphur/aromatic profiles were used to compare the oils, and to correctly differentiate oils from different geographical regions. Py-GC-MS could not differentiate a weathered oil sample and a fresh oil sample from the same source. The results of this study support the findings from a previously developed FTIR method for asphaltene profiling.

AB - A Pyrolysis" Gas Chromatography" Mass Spectrometry (Py-GC-MS) method was developed for the analysis and profiling of crude and heavy fuel oil asphaltenes, for application in oil fingerprinting. Asphaltenes were precipitated from ten geographically different oils using n-pentane, and analysed by Py-GC-MS. Alkane profiles and sulphur/aromatic profiles were used to compare the oils, and to correctly differentiate oils from different geographical regions. Py-GC-MS could not differentiate a weathered oil sample and a fresh oil sample from the same source. The results of this study support the findings from a previously developed FTIR method for asphaltene profiling.

KW - alkanes

KW - environmental forensics

KW - oil spills

KW - polycyclic aromatic hydrocarbons

UR - http://handle.westernsydney.edu.au:8081/1959.7/uws:44983

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DO - 10.1080/15275922.2017.1408163

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JO - Environmental Forensics

JF - Environmental Forensics

IS - 1

ER -

Pyrolysis-GC-MS analysis of crude and heavy fuel oil asphaltenes for application in oil fingerprinting

Abstract

Bibliographical note

UN SDGs

Keywords

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Evaporation and photochemical effects on asphaltene profiling of heavy fuel oil

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Pyrolysis-GC-MS analysis of crude and heavy fuel oil asphaltenes for application in oil fingerprinting

Abstract

Bibliographical note

UN SDGs

Keywords

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Datasets

Evaporation and photochemical effects on asphaltene profiling of heavy fuel oil

Cite this