Raman spectroscopy of some basic chloride containing minerals of lead and copper

Ray L. Frost; Peter A. Williams

Raman spectroscopy of some basic chloride containing minerals of lead and copper

Ray L. Frost
, Peter A. Williams

Research output: Contribution to journal › Article

36 Citations (Scopus)

Abstract

Raman spectroscopy has been used to characterise several lead and mixed cationic-lead minerals including mendipite, perite, laurionite, diabolÃƒÆ’Ã†'Ãƒ"šÃ†'ÃƒÆ’Ã¢â‚¬Å¡Ãƒ"šÃ‚Â©ite, bolÃƒÆ’Ã†'Ãƒ"šÃ†'ÃƒÆ’Ã¢â‚¬Å¡Ãƒ"šÃ‚Â©ite, pseudobolÃƒÆ’Ã†'Ãƒ"šÃ†'ÃƒÆ’Ã¢â‚¬Å¡Ãƒ"šÃ‚Â©ite, chloroxiphite, and cumengÃƒÆ’Ã†'Ãƒ"šÃ†'ÃƒÆ’Ã¢â‚¬Å¡Ãƒ"šÃ‚Â©ite. Raman spectroscopy enables their vibrational spectra to be compared. The low wavenumber region is characterised by the bands assigned to cation-chloride stretching and bending modes. Phosgenite is a mixed chlorideÃƒÂ¢Ã¢"šÂ¬Ã¢â‚¬Å“carbonate mineral and a comparison is made with the molecular structure of the aforementioned minerals. Each mineral shows different hydroxyl stretching vibrational patterns, but some similarity exists in the Raman spectra of the hydroxyl deformation modes. Raman spectroscopy lends itself to the study of these types of minerals in complex mineral systems involving secondary mineral formation.

Original language	English
Number of pages	7
Journal	Spectrochimica acta. Part A\, Molecular and biomolecular spectroscopy
Publication status	Published - 2004

Keywords

Boleite
Cumengeite
Diaboleite
copper
lead
raman spectroscopy

Cite this

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title = "Raman spectroscopy of some basic chloride containing minerals of lead and copper",

abstract = "Raman spectroscopy has been used to characterise several lead and mixed cationic-lead minerals including mendipite, perite, laurionite, diabol{\~A}ƒ{\AE}{\textquoteright}{\~A}†'{\~A}ƒ{"}{\v s}{\~A}†'{\~A}ƒ{\AE}{\textquoteright}{\~A}¢{\^a}‚¬{\AA}¡{\~A}ƒ{"}{\v s}{\~A}‚{\^A}{\textcopyright}ite, bol{\~A}ƒ{\AE}{\textquoteright}{\~A}†'{\~A}ƒ{"}{\v s}{\~A}†'{\~A}ƒ{\AE}{\textquoteright}{\~A}¢{\^a}‚¬{\AA}¡{\~A}ƒ{"}{\v s}{\~A}‚{\^A}{\textcopyright}ite, pseudobol{\~A}ƒ{\AE}{\textquoteright}{\~A}†'{\~A}ƒ{"}{\v s}{\~A}†'{\~A}ƒ{\AE}{\textquoteright}{\~A}¢{\^a}‚¬{\AA}¡{\~A}ƒ{"}{\v s}{\~A}‚{\^A}{\textcopyright}ite, chloroxiphite, and cumeng{\~A}ƒ{\AE}{\textquoteright}{\~A}†'{\~A}ƒ{"}{\v s}{\~A}†'{\~A}ƒ{\AE}{\textquoteright}{\~A}¢{\^a}‚¬{\AA}¡{\~A}ƒ{"}{\v s}{\~A}‚{\^A}{\textcopyright}ite. Raman spectroscopy enables their vibrational spectra to be compared. The low wavenumber region is characterised by the bands assigned to cation-chloride stretching and bending modes. Phosgenite is a mixed chloride{\~A}ƒ{\^A}¢{\~A}¢{"}{\v s}{\^A}¬{\~A}¢{\^a}‚¬{\AA}“carbonate mineral and a comparison is made with the molecular structure of the aforementioned minerals. Each mineral shows different hydroxyl stretching vibrational patterns, but some similarity exists in the Raman spectra of the hydroxyl deformation modes. Raman spectroscopy lends itself to the study of these types of minerals in complex mineral systems involving secondary mineral formation.",

keywords = "Boleite, Cumengeite, Diaboleite, copper, lead, raman spectroscopy",

author = "Frost, \{Ray L.\} and Williams, \{Peter A.\}",

year = "2004",

language = "English",

journal = "Spectrochimica acta. Part A\textbackslash{}, Molecular and biomolecular spectroscopy",

issn = "1386-1425",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Raman spectroscopy of some basic chloride containing minerals of lead and copper

AU - Frost, Ray L.

AU - Williams, Peter A.

PY - 2004

Y1 - 2004

N2 - Raman spectroscopy has been used to characterise several lead and mixed cationic-lead minerals including mendipite, perite, laurionite, diabolÃƒÆ’Ã†'Ãƒ"šÃ†'ÃƒÆ’Ã¢â‚¬Å¡Ãƒ"šÃ‚Â©ite, bolÃƒÆ’Ã†'Ãƒ"šÃ†'ÃƒÆ’Ã¢â‚¬Å¡Ãƒ"šÃ‚Â©ite, pseudobolÃƒÆ’Ã†'Ãƒ"šÃ†'ÃƒÆ’Ã¢â‚¬Å¡Ãƒ"šÃ‚Â©ite, chloroxiphite, and cumengÃƒÆ’Ã†'Ãƒ"šÃ†'ÃƒÆ’Ã¢â‚¬Å¡Ãƒ"šÃ‚Â©ite. Raman spectroscopy enables their vibrational spectra to be compared. The low wavenumber region is characterised by the bands assigned to cation-chloride stretching and bending modes. Phosgenite is a mixed chlorideÃƒÂ¢Ã¢"šÂ¬Ã¢â‚¬Å“carbonate mineral and a comparison is made with the molecular structure of the aforementioned minerals. Each mineral shows different hydroxyl stretching vibrational patterns, but some similarity exists in the Raman spectra of the hydroxyl deformation modes. Raman spectroscopy lends itself to the study of these types of minerals in complex mineral systems involving secondary mineral formation.

AB - Raman spectroscopy has been used to characterise several lead and mixed cationic-lead minerals including mendipite, perite, laurionite, diabolÃƒÆ’Ã†'Ãƒ"šÃ†'ÃƒÆ’Ã¢â‚¬Å¡Ãƒ"šÃ‚Â©ite, bolÃƒÆ’Ã†'Ãƒ"šÃ†'ÃƒÆ’Ã¢â‚¬Å¡Ãƒ"šÃ‚Â©ite, pseudobolÃƒÆ’Ã†'Ãƒ"šÃ†'ÃƒÆ’Ã¢â‚¬Å¡Ãƒ"šÃ‚Â©ite, chloroxiphite, and cumengÃƒÆ’Ã†'Ãƒ"šÃ†'ÃƒÆ’Ã¢â‚¬Å¡Ãƒ"šÃ‚Â©ite. Raman spectroscopy enables their vibrational spectra to be compared. The low wavenumber region is characterised by the bands assigned to cation-chloride stretching and bending modes. Phosgenite is a mixed chlorideÃƒÂ¢Ã¢"šÂ¬Ã¢â‚¬Å“carbonate mineral and a comparison is made with the molecular structure of the aforementioned minerals. Each mineral shows different hydroxyl stretching vibrational patterns, but some similarity exists in the Raman spectra of the hydroxyl deformation modes. Raman spectroscopy lends itself to the study of these types of minerals in complex mineral systems involving secondary mineral formation.

KW - Boleite

KW - Cumengeite

KW - Diaboleite

KW - copper

KW - lead

KW - raman spectroscopy

UR - http://handle.uws.edu.au:8081/1959.7/9842

M3 - Article

SN - 1386-1425

JO - Spectrochimica acta. Part A\, Molecular and biomolecular spectroscopy

JF - Spectrochimica acta. Part A\, Molecular and biomolecular spectroscopy

ER -

Raman spectroscopy of some basic chloride containing minerals of lead and copper

Abstract

Keywords

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