TY - JOUR
T1 - Recent developments in the metallo-supramolecular chemistry of oligo-β-diketonato ligands
AU - Brock, Aidan J.
AU - Clegg, Jack K.
AU - Li, Feng
AU - Lindoy, Leonard F.
PY - 2018
Y1 - 2018
N2 - Classical β-diketone ligands have been well demonstrated to exhibit a rich metal coordination chemistry yielding metal complexes displaying a variety of properties. The investigation of polydentate ligand derivatives containing more than one β-diketone domain, and in many instances also incorporating additional donor sites, have been demonstrated to react with a range of metal ion types to yield a wide range of metallo-supramolecular topologies. These include metallocyclic platforms, triangles, squares, cubes, helicates, tetrahedrons as well as other intricate structures that include a universal 3-ravel. In this report we cover the published literature in the area from 2008 with emphasis on the synthetic strategies employed as well as on the diverse structures of the metallo-supramolecular products obtained.
AB - Classical β-diketone ligands have been well demonstrated to exhibit a rich metal coordination chemistry yielding metal complexes displaying a variety of properties. The investigation of polydentate ligand derivatives containing more than one β-diketone domain, and in many instances also incorporating additional donor sites, have been demonstrated to react with a range of metal ion types to yield a wide range of metallo-supramolecular topologies. These include metallocyclic platforms, triangles, squares, cubes, helicates, tetrahedrons as well as other intricate structures that include a universal 3-ravel. In this report we cover the published literature in the area from 2008 with emphasis on the synthetic strategies employed as well as on the diverse structures of the metallo-supramolecular products obtained.
KW - coordination polymers
KW - ketones
KW - self-assembly (chemistry)
KW - triangle
UR - http://handle.westernsydney.edu.au:8081/1959.7/uws:44860
U2 - 10.1016/j.ccr.2017.11.007
DO - 10.1016/j.ccr.2017.11.007
M3 - Article
SN - 0010-8545
VL - 375
SP - 106
EP - 133
JO - Coordination Chemistry Reviews
JF - Coordination Chemistry Reviews
ER -