Retention of polycyclic aromatic hydrocarbons on propyl-phenyl stationary phases in reversed-phase high performance liquid chromatography

Sindy Kayillo; Gary R. Dennis; Ross A. Shalliker

doi:10.1016/j.chroma.2007.03.004

Retention of polycyclic aromatic hydrocarbons on propyl-phenyl stationary phases in reversed-phase high performance liquid chromatography

Sindy Kayillo, Gary R. Dennis, Ross A. Shalliker

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Abstract

A study on the retention of PAHs on three Propyl-phenyl stationary phases was conducted, assessing absolute retention, selectivity, retention correlation and thermodynamic behaviour. The chromatographic retention data revealed that each of the three Propyl-phenyl columns exhibited differences in absolute retention, however, comparison of the compensation temperatures derived from enthalpy-entropy compensation plots showed that the underlying processes responsible for the retention on these columns were the same.

Original language	English
Pages (from-to)	168-176
Number of pages	9
Journal	Journal of Chromatography A
Volume	1148
Issue number	2
DOIs	https://doi.org/10.1016/j.chroma.2007.03.004
Publication status	Published - 4 May 2007

Keywords

HPLC
polycyclic aromatic hydrocarbons
propyl-phenyl stationary phases
reproducibility
retention
thermodynamics

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10.1016/j.chroma.2007.03.004

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title = "Retention of polycyclic aromatic hydrocarbons on propyl-phenyl stationary phases in reversed-phase high performance liquid chromatography",

abstract = "A study on the retention of PAHs on three Propyl-phenyl stationary phases was conducted, assessing absolute retention, selectivity, retention correlation and thermodynamic behaviour. The chromatographic retention data revealed that each of the three Propyl-phenyl columns exhibited differences in absolute retention, however, comparison of the compensation temperatures derived from enthalpy-entropy compensation plots showed that the underlying processes responsible for the retention on these columns were the same.",

keywords = "HPLC, polycyclic aromatic hydrocarbons, propyl-phenyl stationary phases, reproducibility, retention, thermodynamics",

author = "Sindy Kayillo and Dennis, {Gary R.} and Shalliker, {Ross A.}",

year = "2007",

month = may,

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doi = "10.1016/j.chroma.2007.03.004",

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volume = "1148",

pages = "168--176",

journal = "Journal of Chromatography A",

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TY - JOUR

T1 - Retention of polycyclic aromatic hydrocarbons on propyl-phenyl stationary phases in reversed-phase high performance liquid chromatography

AU - Kayillo, Sindy

AU - Dennis, Gary R.

AU - Shalliker, Ross A.

PY - 2007/5/4

Y1 - 2007/5/4

N2 - A study on the retention of PAHs on three Propyl-phenyl stationary phases was conducted, assessing absolute retention, selectivity, retention correlation and thermodynamic behaviour. The chromatographic retention data revealed that each of the three Propyl-phenyl columns exhibited differences in absolute retention, however, comparison of the compensation temperatures derived from enthalpy-entropy compensation plots showed that the underlying processes responsible for the retention on these columns were the same.

AB - A study on the retention of PAHs on three Propyl-phenyl stationary phases was conducted, assessing absolute retention, selectivity, retention correlation and thermodynamic behaviour. The chromatographic retention data revealed that each of the three Propyl-phenyl columns exhibited differences in absolute retention, however, comparison of the compensation temperatures derived from enthalpy-entropy compensation plots showed that the underlying processes responsible for the retention on these columns were the same.

KW - HPLC

KW - polycyclic aromatic hydrocarbons

KW - propyl-phenyl stationary phases

KW - reproducibility

KW - retention

KW - thermodynamics

UR - http://handle.uws.edu.au:8081/1959.7/40862

U2 - 10.1016/j.chroma.2007.03.004

DO - 10.1016/j.chroma.2007.03.004

M3 - Article

SN - 0021-9673

VL - 1148

SP - 168

EP - 176

JO - Journal of Chromatography A

JF - Journal of Chromatography A

IS - 2

ER -

Retention of polycyclic aromatic hydrocarbons on propyl-phenyl stationary phases in reversed-phase high performance liquid chromatography

Abstract

Keywords

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