Self-assembled Co(II) molecular squares incorporating the bridging ligand 4,7-phenanthrolino-5,6:5"²,6"²-pyrazine

Feng Li; Jack K. Clegg; Deanna M. D&apos;Alessandro; Laurence Goux-Capes; Natasha F. Sciortino; Tony D. Keene; Cameron J. Kepert

doi:10.1039/c1dt11254f

Self-assembled Co(II) molecular squares incorporating the bridging ligand 4,7-phenanthrolino-5,6:5"²,6"²-pyrazine

Feng Li
, Jack K. Clegg
, Deanna M. D'Alessandro
, Laurence Goux-Capes
, Natasha F. Sciortino
, Tony D. Keene
, Cameron J. Kepert

School of Science

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Three high-spin tetranuclear cobalt(ii) complexes have been prepared with the bridging ligand 4,7-phenanthrolino-5,6:5"²,6"²-pyrazine (ppz) through metal-ion directed self-assembly. The complexes differ by the incorporation of three different coordinating anions: chloride, thiocyanide and selenocyanide. The physical properties of these complexes have been investigated in detail.

Original language	English
Pages (from-to)	12388-12393
Number of pages	6
Journal	Dalton Transactions
Volume	40
Issue number	45
DOIs	https://doi.org/10.1039/c1dt11254f
Publication status	Published - 2011

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title = "Self-assembled Co(II) molecular squares incorporating the bridging ligand 4,7-phenanthrolino-5,6:5{"}²,6{"}²-pyrazine",

abstract = "Three high-spin tetranuclear cobalt(ii) complexes have been prepared with the bridging ligand 4,7-phenanthrolino-5,6:5{"}²,6{"}²-pyrazine (ppz) through metal-ion directed self-assembly. The complexes differ by the incorporation of three different coordinating anions: chloride, thiocyanide and selenocyanide. The physical properties of these complexes have been investigated in detail.",

author = "Feng Li and Clegg, \{Jack K.\} and D\'Alessandro, \{Deanna M.\} and Laurence Goux-Capes and Sciortino, \{Natasha F.\} and Keene, \{Tony D.\} and Kepert, \{Cameron J.\}",

year = "2011",

doi = "10.1039/c1dt11254f",

language = "English",

volume = "40",

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journal = "Dalton Transactions",

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publisher = "Royal Society of Chemistry",

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T1 - Self-assembled Co(II) molecular squares incorporating the bridging ligand 4,7-phenanthrolino-5,6:5"²,6"²-pyrazine

AU - Li, Feng

AU - Clegg, Jack K.

AU - D'Alessandro, Deanna M.

AU - Goux-Capes, Laurence

AU - Sciortino, Natasha F.

AU - Keene, Tony D.

AU - Kepert, Cameron J.

PY - 2011

Y1 - 2011

N2 - Three high-spin tetranuclear cobalt(ii) complexes have been prepared with the bridging ligand 4,7-phenanthrolino-5,6:5"²,6"²-pyrazine (ppz) through metal-ion directed self-assembly. The complexes differ by the incorporation of three different coordinating anions: chloride, thiocyanide and selenocyanide. The physical properties of these complexes have been investigated in detail.

AB - Three high-spin tetranuclear cobalt(ii) complexes have been prepared with the bridging ligand 4,7-phenanthrolino-5,6:5"²,6"²-pyrazine (ppz) through metal-ion directed self-assembly. The complexes differ by the incorporation of three different coordinating anions: chloride, thiocyanide and selenocyanide. The physical properties of these complexes have been investigated in detail.

UR - http://handle.uws.edu.au:8081/1959.7/552286

U2 - 10.1039/c1dt11254f

DO - 10.1039/c1dt11254f

M3 - Article

SN - 1477-9226

VL - 40

SP - 12388

EP - 12393

JO - Dalton Transactions

JF - Dalton Transactions

IS - 45

ER -

Self-assembled Co(II) molecular squares incorporating the bridging ligand 4,7-phenanthrolino-5,6:5"²,6"²-pyrazine

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