Self-assembly of a unique 3d/4f heterometallic square prismatic box-like coordination cage

Li Li; Yingjie Zhang; Maxim Avdeev; Leonard F. Lindoy; David G. Harman; Rongkun Zheng; Zhenxiang Cheng; Janice R. Aldrich-Wright; Feng Li

Self-assembly of a unique 3d/4f heterometallic square prismatic box-like coordination cage

Li Li, Yingjie Zhang, Maxim Avdeev, Leonard F. Lindoy, David G. Harman, Rongkun Zheng, Zhenxiang Cheng, Janice R. Aldrich-Wright, Feng Li

Western Sydney University

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

We present the synthesis and characterization of a unique, slightly distorted square prismatic, box-like coordination cage of type [Cu6Dy8L8(MeOH)8(H2O)6](NO3)12•χ solvent obtained via the supramolecular assembly between a non-centrosymmetric Dy(iii) metalloligand and Cu(ii) nitrate. Magnetic susceptibility measurements indicate that the complex behaves as a single-molecule magnet.

Original language	English
Pages (from-to)	9407-9411
Number of pages	5
Journal	Dalton Transactions
Volume	45
Issue number	23
Publication status	Published - 2016

Bibliographical note

Publisher Copyright:
© 2016 The Royal Society of Chemistry.

Keywords

coordination cages

Cite this

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title = "Self-assembly of a unique 3d/4f heterometallic square prismatic box-like coordination cage",

abstract = "We present the synthesis and characterization of a unique, slightly distorted square prismatic, box-like coordination cage of type [Cu6Dy8L8(MeOH)8(H2O)6](NO3)12•χ solvent obtained via the supramolecular assembly between a non-centrosymmetric Dy(iii) metalloligand and Cu(ii) nitrate. Magnetic susceptibility measurements indicate that the complex behaves as a single-molecule magnet.",

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author = "Li Li and Yingjie Zhang and Maxim Avdeev and Lindoy, {Leonard F.} and Harman, {David G.} and Rongkun Zheng and Zhenxiang Cheng and Aldrich-Wright, {Janice R.} and Feng Li",

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T1 - Self-assembly of a unique 3d/4f heterometallic square prismatic box-like coordination cage

AU - Li, Li

AU - Zhang, Yingjie

AU - Avdeev, Maxim

AU - Lindoy, Leonard F.

AU - Harman, David G.

AU - Zheng, Rongkun

AU - Cheng, Zhenxiang

AU - Aldrich-Wright, Janice R.

AU - Li, Feng

PY - 2016

Y1 - 2016

N2 - We present the synthesis and characterization of a unique, slightly distorted square prismatic, box-like coordination cage of type [Cu6Dy8L8(MeOH)8(H2O)6](NO3)12•χ solvent obtained via the supramolecular assembly between a non-centrosymmetric Dy(iii) metalloligand and Cu(ii) nitrate. Magnetic susceptibility measurements indicate that the complex behaves as a single-molecule magnet.

AB - We present the synthesis and characterization of a unique, slightly distorted square prismatic, box-like coordination cage of type [Cu6Dy8L8(MeOH)8(H2O)6](NO3)12•χ solvent obtained via the supramolecular assembly between a non-centrosymmetric Dy(iii) metalloligand and Cu(ii) nitrate. Magnetic susceptibility measurements indicate that the complex behaves as a single-molecule magnet.

KW - coordination cages

UR - http://handle.uws.edu.au:8081/1959.7/uws:36326

M3 - Article

SN - 1477-9226

VL - 45

SP - 9407

EP - 9411

JO - Dalton Transactions

JF - Dalton Transactions

IS - 23

ER -

Self-assembly of a unique 3d/4f heterometallic square prismatic box-like coordination cage

Abstract

Bibliographical note

Keywords

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