Self-assembly of an imidazolate-bridged FeIII/CuII heterometallic cage

Florian Reichel; Jack K. Clegg; Karsten Gloe; Kerstin Gloe; Jan J. Weigand; Jason K. Reynolds; Chun-Guang Li; Janice R. Aldrich-Wright; Cameron J. Kepert; Leonard F. Lindoy; Hong-Chang Yao; Feng Li

doi:10.1021/ic402686s

Self-assembly of an imidazolate-bridged FeIII/CuII heterometallic cage

Florian Reichel, Jack K. Clegg, Karsten Gloe, Kerstin Gloe, Jan J. Weigand, Jason K. Reynolds, Chun-Guang Li, Janice R. Aldrich-Wright, Cameron J. Kepert, Leonard F. Lindoy, Hong-Chang Yao, Feng Li

Research output: Contribution to journal › Article › peer-review

67 Citations (Scopus)

Abstract

A rare, discrete, mixed-valent, heterometallic Fe(III)/Cu(II) cage, [Cu6Fe8L8](ClO4)12 Ï‡solvent (H3L = tris{[2-{(imidazole-4-yl)methylidene}amino]ethyl} amine), was designed and synthesized via metal-ion-directed self-assembly with neutral tripodal metalloligands. The formation of this coordination cage was demonstrated by X-ray crystallography, ESI mass spectrometry, FT-IR, and UV-vis-NIR spectroscopy.

Original language	English
Pages (from-to)	688-690
Number of pages	3
Journal	Inorganic Chemistry
Volume	53
Issue number	2
DOIs	https://doi.org/10.1021/ic402686s
Publication status	Published - 2014

Keywords

Spin-crossover
Iron complexes
Principles
Receptors
Cu

Access to Document

10.1021/ic402686s

Cite this

@article{aebf8948c66a4d5c84e4aa99eacf5be6,

title = "Self-assembly of an imidazolate-bridged FeIII/CuII heterometallic cage",

abstract = "A rare, discrete, mixed-valent, heterometallic Fe(III)/Cu(II) cage, [Cu6Fe8L8](ClO4)12 {\"I}‡solvent (H3L = tris{[2-{(imidazole-4-yl)methylidene}amino]ethyl} amine), was designed and synthesized via metal-ion-directed self-assembly with neutral tripodal metalloligands. The formation of this coordination cage was demonstrated by X-ray crystallography, ESI mass spectrometry, FT-IR, and UV-vis-NIR spectroscopy.",

keywords = "Spin-crossover, Iron complexes, Principles, Receptors, Cu",

author = "Florian Reichel and Clegg, {Jack K.} and Karsten Gloe and Kerstin Gloe and Weigand, {Jan J.} and Reynolds, {Jason K.} and Chun-Guang Li and Aldrich-Wright, {Janice R.} and Kepert, {Cameron J.} and Lindoy, {Leonard F.} and Hong-Chang Yao and Feng Li",

year = "2014",

doi = "10.1021/ic402686s",

language = "English",

volume = "53",

pages = "688--690",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "2",

}

TY - JOUR

T1 - Self-assembly of an imidazolate-bridged FeIII/CuII heterometallic cage

AU - Reichel, Florian

AU - Clegg, Jack K.

AU - Gloe, Karsten

AU - Gloe, Kerstin

AU - Weigand, Jan J.

AU - Reynolds, Jason K.

AU - Li, Chun-Guang

AU - Aldrich-Wright, Janice R.

AU - Kepert, Cameron J.

AU - Lindoy, Leonard F.

AU - Yao, Hong-Chang

AU - Li, Feng

PY - 2014

Y1 - 2014

N2 - A rare, discrete, mixed-valent, heterometallic Fe(III)/Cu(II) cage, [Cu6Fe8L8](ClO4)12 Ï‡solvent (H3L = tris{[2-{(imidazole-4-yl)methylidene}amino]ethyl} amine), was designed and synthesized via metal-ion-directed self-assembly with neutral tripodal metalloligands. The formation of this coordination cage was demonstrated by X-ray crystallography, ESI mass spectrometry, FT-IR, and UV-vis-NIR spectroscopy.

AB - A rare, discrete, mixed-valent, heterometallic Fe(III)/Cu(II) cage, [Cu6Fe8L8](ClO4)12 Ï‡solvent (H3L = tris{[2-{(imidazole-4-yl)methylidene}amino]ethyl} amine), was designed and synthesized via metal-ion-directed self-assembly with neutral tripodal metalloligands. The formation of this coordination cage was demonstrated by X-ray crystallography, ESI mass spectrometry, FT-IR, and UV-vis-NIR spectroscopy.

KW - Spin-crossover

KW - Iron complexes

KW - Principles

KW - Receptors

KW - Cu

UR - http://handle.uws.edu.au:8081/1959.7/538372

U2 - 10.1021/ic402686s

DO - 10.1021/ic402686s

M3 - Article

C2 - 24393071

SN - 0020-1669

VL - 53

SP - 688

EP - 690

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 2

ER -

Self-assembly of an imidazolate-bridged FeIII/CuII heterometallic cage

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this