The atacamite family of minerals : a testbed for quantum spin liquids

Thomas Malcherek, Mark D. Welch, Peter A. Williams

Research output: Contribution to journalArticlepeer-review

16 Citations (Scopus)

Abstract

Polymorphism of Cu 2 (OH) 3 Cl coupled with partial substitution of Jahn–Teller active Cu 2+ by other divalent metal cations gives rise to the complex mineralogy of the atacamite family of secondary basic copper chlorides. Herbertsmithite, Cu 3 Zn(OH) 6 Cl 2 , in which Zn substitutes for one quarter of the Cu atoms, provides a lattice of corner-sharing triangles of paramagnetic Cu 2+ (spin ½) cations, rendering the mineral a perfect realization of a kagome antiferromagnet. Geometric frustration of conventional antiferromagnetism is expected to give rise to exotic ground states, with dynamic magnetic structures that might turn out to be physical realizations of quantum spin liquids. In this paper, a synopsis of the key topological, compositional and behavioural features of minerals in the atacamite family is given, with emphasis on the kagome character of the resulting lattice of Cu 2+ cations.
Original languageEnglish
Pages (from-to)519-526
Number of pages8
JournalActa Crystallographica. Section B: Structural Science, Crystal Engineering and Materials
Volume74
Issue number6
DOIs
Publication statusPublished - 2018

Keywords

  • copper
  • minerals
  • polymorphism
  • quantum electrodynamics
  • quantum theory

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