TY - JOUR
T1 - The variation of Mn-dopant distribution state with x and its effect on the magnetic coupling mechanism in Zn1-xMnxO nanocrystals
AU - Cheng, Yan
AU - Hao, Wei-Chang
AU - Li, Wen-Xian
AU - Xu, Huai-Zhe
AU - Chen, Rui
AU - Dou, Shi-Xue
PY - 2013
Y1 - 2013
N2 - Zn1-xMnxO (x = 0.0005, 0.001, 0.005, 0.01, 0.02) nanocrystals are synthesized by using a wet chemical process. The coordination environment of Mn is characterized by X-ray photoelectron spectroscopy, Raman spectroscopy, and its X-ray absorption fine structure. It is found that the solubility of substitutional Mn in a ZnO lattice is very low, which is less than 0.4%. Mn ions first dissolve into the substitutional sites in the ZnO lattice, thereby forming Mn2+O4 tetrahedral coordination when x ≤ 0.001, then entering into the interstitial sites and forming Mn 3+O6 octahedral coordination when x ≥ 0.005. All the samples exhibit paramagnetic behaviors at room temperature, and antiferromagnetic coupling can be observed below 100 K.
AB - Zn1-xMnxO (x = 0.0005, 0.001, 0.005, 0.01, 0.02) nanocrystals are synthesized by using a wet chemical process. The coordination environment of Mn is characterized by X-ray photoelectron spectroscopy, Raman spectroscopy, and its X-ray absorption fine structure. It is found that the solubility of substitutional Mn in a ZnO lattice is very low, which is less than 0.4%. Mn ions first dissolve into the substitutional sites in the ZnO lattice, thereby forming Mn2+O4 tetrahedral coordination when x ≤ 0.001, then entering into the interstitial sites and forming Mn 3+O6 octahedral coordination when x ≥ 0.005. All the samples exhibit paramagnetic behaviors at room temperature, and antiferromagnetic coupling can be observed below 100 K.
UR - http://handle.uws.edu.au:8081/1959.7/536811
U2 - 10.1088/1674-1056/22/10/107501
DO - 10.1088/1674-1056/22/10/107501
M3 - Article
SN - 1674-1056
VL - 22
JO - Chinese Physics B
JF - Chinese Physics B
IS - 10
M1 - 107501
ER -